(1a,6a,7a,7aβ)-2,3,5,6,7,7a-Hexahydro-1,6-epoxy-1H-pyrrolizin-7-ol

Richard S. Glass; Donald R. Deardorff; Nhu Y.T. Stessman; Michael D. Carducci

doi:10.1107/S1600536803016970

(1a,6a,7a,7aβ)-2,3,5,6,7,7a-Hexahydro-1,6-epoxy-1H-pyrrolizin-7-ol

Richard S. Glass, Donald R. Deardorff, Nhu Y.T. Stessman, Michael D. Carducci

Chemistry and Biochemistry

Research output: Contribution to journal › Article

1 Scopus citations

Abstract

The C₇H₁₁NO₂ compound, an intermediate in a synthetic approach to the pyrrolizidine alkaloid loline was discussed. The compound has a brendane skeleton with a 91.8(2)° bond angle for the bridging carbon bearing the OH group. The x-ray show that the molecule was an analog of brendane. The results show that the molecules of compound form infinite linear chains through hydrogen bonding of the alcohol moiety of one molecule with the amine moiety of the next molecule.

Original language	English (US)
Pages (from-to)	o1270-o1271
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	9
DOIs	https://doi.org/10.1107/S1600536803016970
State	Published - Sep 1 2003

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Glass, R. S., Deardorff, D. R., Stessman, N. Y. T., & Carducci, M. D. (2003). (1a,6a,7a,7aβ)-2,3,5,6,7,7a-Hexahydro-1,6-epoxy-1H-pyrrolizin-7-ol. Acta Crystallographica Section E: Structure Reports Online, 59(9), o1270-o1271. https://doi.org/10.1107/S1600536803016970

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abstract = "The C7H11NO2 compound, an intermediate in a synthetic approach to the pyrrolizidine alkaloid loline was discussed. The compound has a brendane skeleton with a 91.8(2)° bond angle for the bridging carbon bearing the OH group. The x-ray show that the molecule was an analog of brendane. The results show that the molecules of compound form infinite linear chains through hydrogen bonding of the alcohol moiety of one molecule with the amine moiety of the next molecule.",

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AU - Carducci, Michael D.

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