A detrital model for the origin of gold and sulfides in the Witwatersrand basin based on Re-Os isotopes

Jason Kirk, Joaquin Ruiz, John Chesley, Spencer Titley, John Walshe

Research output: Contribution to journalArticle

61 Citations (Scopus)

Abstract

The Re-Os systematics of gold and sulfides from the Witwatersrand basin were utilized to determine whether the gold is detrital or was introduced by hydrothermal solutions from outside the basin. Gold from a gravity concentrate from the Western Areas Gold Plant and gold from the Vaal Reef have very high Os concentrations of approximately 73 to 10000 ppb and 3 to 32 ppb Re, resulting in 187 Re/188Os ratios of 0.010 to 0.185. The gold has subchondritic 187Os/188Os ratios between 0.1056 to 0.1099 and an average value of 0.1067. Rhenium depletion ages (TRD) range from 3.5 Ga to 2.9 Ga, with a median age of 3.3 Ga. Pyrite from the Vaal Reef have Os concentrations ranging from 0.26 to 0.68 ppb, Re concentrations of 1.7 to 2.8 ppb and 187Re/188Os ratios of approximately 14 to 87. The pyrite samples have measured 187Os/188Os ratios of 0.84 to 4.7 and define an isochron with an age of 2.99 ± 0.11 Ga (MSWD = 0.77). The Os isotopic data from the direct measurement of gold preclude introduction of gold to the Witwatersrand basin from crustally derived metamorphic or hydrothermal fluids between 2.7 to 2.0 Ga. The unradiogenic 187Os/188Os ratios, old TRD ages of the Western Areas and Vaal Reef gold samples, as well as the contemporaneously old age of the Vaal Reef pyrite are consistent with detrital deposition of gold during the formation of the Witswatersrand basin. The Os data will allow for minor hydrothermal remobilization and/or overprinting of hydrothermal gold on preexisting detrital gold grains but does not support the introduction of gold solely by hydrothermal fluids.

Original languageEnglish (US)
Pages (from-to)2149-2159
Number of pages11
JournalGeochimica et Cosmochimica Acta
Volume65
Issue number13
DOIs
StatePublished - 2001

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Sulfides
Isotopes
Gold
gold
sulfide
isotope
basin
Reefs
reef
pyrite
hydrothermal fluid
Rhenium
rhenium
Fluids
overprinting
remobilization
Gravitation

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

A detrital model for the origin of gold and sulfides in the Witwatersrand basin based on Re-Os isotopes. / Kirk, Jason; Ruiz, Joaquin; Chesley, John; Titley, Spencer; Walshe, John.

In: Geochimica et Cosmochimica Acta, Vol. 65, No. 13, 2001, p. 2149-2159.

Research output: Contribution to journalArticle

Kirk, Jason ; Ruiz, Joaquin ; Chesley, John ; Titley, Spencer ; Walshe, John. / A detrital model for the origin of gold and sulfides in the Witwatersrand basin based on Re-Os isotopes. In: Geochimica et Cosmochimica Acta. 2001 ; Vol. 65, No. 13. pp. 2149-2159.
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abstract = "The Re-Os systematics of gold and sulfides from the Witwatersrand basin were utilized to determine whether the gold is detrital or was introduced by hydrothermal solutions from outside the basin. Gold from a gravity concentrate from the Western Areas Gold Plant and gold from the Vaal Reef have very high Os concentrations of approximately 73 to 10000 ppb and 3 to 32 ppb Re, resulting in 187 Re/188Os ratios of 0.010 to 0.185. The gold has subchondritic 187Os/188Os ratios between 0.1056 to 0.1099 and an average value of 0.1067. Rhenium depletion ages (TRD) range from 3.5 Ga to 2.9 Ga, with a median age of 3.3 Ga. Pyrite from the Vaal Reef have Os concentrations ranging from 0.26 to 0.68 ppb, Re concentrations of 1.7 to 2.8 ppb and 187Re/188Os ratios of approximately 14 to 87. The pyrite samples have measured 187Os/188Os ratios of 0.84 to 4.7 and define an isochron with an age of 2.99 ± 0.11 Ga (MSWD = 0.77). The Os isotopic data from the direct measurement of gold preclude introduction of gold to the Witwatersrand basin from crustally derived metamorphic or hydrothermal fluids between 2.7 to 2.0 Ga. The unradiogenic 187Os/188Os ratios, old TRD ages of the Western Areas and Vaal Reef gold samples, as well as the contemporaneously old age of the Vaal Reef pyrite are consistent with detrital deposition of gold during the formation of the Witswatersrand basin. The Os data will allow for minor hydrothermal remobilization and/or overprinting of hydrothermal gold on preexisting detrital gold grains but does not support the introduction of gold solely by hydrothermal fluids.",
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