A generalization of the state-specific complete-active-space coupled-cluster method for calculating electronic excited states

Dmitry I. Lyakh, Vladimir V. Ivanov, Ludwik Adamowicz

Research output: Contribution to journalArticle

42 Scopus citations

Abstract

The complete-active-space coupled-cluster approach with single and double excitations (CASCCSD) based on the ansatz of Oliphant and Adamowicz [J. Chem. Phys. 94, 1229 (1991); 96, 3739 (1992)] is used to derive an approach termed XCASCCSD for calculating potential energy surfaces of ground and excited electronic states with different multiplicities and symmetries. The XCASCCSD approach explicitly includes a procedure for spin and spatial orbital-momentum symmetry adaptation of the wave function that has allowed us to consider states with degenerate formal references. The XCASCCSD method is applied to calculate potential energy surfaces of the ground and some lowest singlet and triplet excited states of the FH and C2 molecules. Some states of C2 are known to have a very strong "multireference" character making their description difficult with single-reference methods. The problem of the change of the formal reference determinant along the potential energy surface is discussed. Also, vertical excitation energies of formaldehyde calculated with the XCASCCSD approach are presented.

Original languageEnglish (US)
Article number074101
JournalJournal of Chemical Physics
Volume128
Issue number7
DOIs
StatePublished - Mar 3 2008

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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