Abstract
(Graph Presented) Dispersion of the Verdet constant is determined experimentally and theoretically for benzene, toluene, and p-xylene as pure liquids. Both theory and experiment show that the amplitude of the Verdet constant decreases when methyl groups are added to the benzene ring, due to the decreasing number density with the increasing size of the molecule. The picture shows the Verdet constants of benzene, toluene, and p-xylene as a function of wavelength and compares theory with experiment.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1654-1656 |
| Number of pages | 3 |
| Journal | ChemPhysChem |
| Volume | 7 |
| Issue number | 8 |
| DOIs | |
| State | Published - Aug 11 2006 |
Keywords
- Density functional calculations
- Faraday effect
- Magnetic properties
- Verdet constants
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Physical and Theoretical Chemistry
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Cite this
Botek, E., Champagne, B., Verbiest, T., Gangopadhyay, P., & Persoons, A. (2006). A joint theoretical-experimental investigation of the Faraday effect in benzene, toluene, and p-xylene. ChemPhysChem, 7(8), 1654-1656. https://doi.org/10.1002/cphc.200600221