A quenchable superhard carbon phase synthesized by cold compression of carbon nanotubes

Zhongwu Wang, Yusheng Zhao, Kimberly Tait, Xiaozhou Liao, David Schiferl, Changsheng Zha, Robert T. Downs, Jiang Qian, Yuntian Zhu, Tongde Shen

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121 Scopus citations

Abstract

A quenchable superhard high-pressure carbon phase was synthesized by cold compression of carbon nanotubes. Carbon nanotubes were placed in a diamond anvil cell, and x-ray diffraction measurements were conducted to pressures of ≈100 GPa. A hexagonal carbon phase was formed at ≈75 GPa and preserved at room conditions. X-ray and transmission electron microscopy electron diffraction, as well as Raman spectroscopy at ambient conditions, explicitly indicate that this phase is a sp3-rich hexagonal carbon polymorph, rather than hexagonal diamond. The cell parameters were refined to a0 = 2.496(4) Å, c0 = 4.123(8) Å, and V0 = 22.24(7) Å3. There is a significant ratio of defects in this nonhomogeneous sample that contains regions with different stacking faults. In addition to the possibly existing amorphous carbon, an average density was estimated to be 3.6 ± 0.2 g/cm3, which is at least compatible to that of diamond (3.52 g/cm3). The bulk modulus was determined to be 447 GPa at fixed K′=4, slightly greater than the reported value for diamond of ≈440-442 GPa. An indented mark, along with radial cracks on the diamond anvils, demonstrates that this hexagonal carbon is a superhard material, at least comparable in hardness to cubic diamond.

Original languageEnglish (US)
Pages (from-to)13699-13702
Number of pages4
JournalProceedings of the National Academy of Sciences of the United States of America
Volume101
Issue number38
DOIs
StatePublished - Sep 21 2004

ASJC Scopus subject areas

  • General

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