A Schiff base expanded porphyrin macrocycle that acts as a versatile binucleating ligand for late first-row transition metals

Jonathan L. Sessler, Elisa Tomat, Tarak D. Mody, Vincent M. Lynch, Jacqueline M. Veauthier, Utkir Mirsaidov, John T. Markert

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

The coordination chemistry of the Schiff base polypyrrolic octaaza macrocycle 1 toward late first-row transition metals was investigated. Binuclear complexes with the divalent cations Ni(II), Cu(II), and Zn(II) and with the monovalent cation Cu(I) were prepared and characterized. Air oxidation of the Cu(I) ions in the latter complex to their divalent oxidation state resulted in a change in the coordination mode relative to the macrocycle.

Original languageEnglish (US)
Pages (from-to)2125-2127
Number of pages3
JournalInorganic Chemistry
Volume44
Issue number7
DOIs
StatePublished - Apr 7 2005
Externally publishedYes

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Schiff Bases
Porphyrins
porphyrins
imines
Transition metals
transition metals
Ligands
cations
Monovalent Cations
Oxidation
ligands
oxidation
Divalent Cations
Ions
chemistry
air
Air
ions
macrocycle 1

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

A Schiff base expanded porphyrin macrocycle that acts as a versatile binucleating ligand for late first-row transition metals. / Sessler, Jonathan L.; Tomat, Elisa; Mody, Tarak D.; Lynch, Vincent M.; Veauthier, Jacqueline M.; Mirsaidov, Utkir; Markert, John T.

In: Inorganic Chemistry, Vol. 44, No. 7, 07.04.2005, p. 2125-2127.

Research output: Contribution to journalArticle

Sessler, Jonathan L. ; Tomat, Elisa ; Mody, Tarak D. ; Lynch, Vincent M. ; Veauthier, Jacqueline M. ; Mirsaidov, Utkir ; Markert, John T. / A Schiff base expanded porphyrin macrocycle that acts as a versatile binucleating ligand for late first-row transition metals. In: Inorganic Chemistry. 2005 ; Vol. 44, No. 7. pp. 2125-2127.
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