Accurate quantum probabilities and threshold behavior of the H+O 2 combustion reaction

Russell T. Pack, Eric Butcher, Gregory A. Parker

Research output: Contribution to journalArticle

94 Citations (Scopus)

Abstract

We report accurate 3D quantum reaction probabilities for the H+O 2 combustion reaction and find that they are resonance dominated and rise linearly above threshold. The reaction probability is not enhanced by vibrational or rotational excitation of the reactants but does increase above the threshold for vibrationally excited products.

Original languageEnglish (US)
Pages (from-to)9310-9313
Number of pages4
JournalThe Journal of Chemical Physics
Volume99
Issue number11
StatePublished - 1993
Externally publishedYes

Fingerprint

thresholds
products
excitation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Accurate quantum probabilities and threshold behavior of the H+O 2 combustion reaction. / Pack, Russell T.; Butcher, Eric; Parker, Gregory A.

In: The Journal of Chemical Physics, Vol. 99, No. 11, 1993, p. 9310-9313.

Research output: Contribution to journalArticle

@article{7e01e29430a34392b4b4be6ee3c8b727,
title = "Accurate quantum probabilities and threshold behavior of the H+O 2 combustion reaction",
abstract = "We report accurate 3D quantum reaction probabilities for the H+O 2 combustion reaction and find that they are resonance dominated and rise linearly above threshold. The reaction probability is not enhanced by vibrational or rotational excitation of the reactants but does increase above the threshold for vibrationally excited products.",
author = "Pack, {Russell T.} and Eric Butcher and Parker, {Gregory A.}",
year = "1993",
language = "English (US)",
volume = "99",
pages = "9310--9313",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "11",

}

TY - JOUR

T1 - Accurate quantum probabilities and threshold behavior of the H+O 2 combustion reaction

AU - Pack, Russell T.

AU - Butcher, Eric

AU - Parker, Gregory A.

PY - 1993

Y1 - 1993

N2 - We report accurate 3D quantum reaction probabilities for the H+O 2 combustion reaction and find that they are resonance dominated and rise linearly above threshold. The reaction probability is not enhanced by vibrational or rotational excitation of the reactants but does increase above the threshold for vibrationally excited products.

AB - We report accurate 3D quantum reaction probabilities for the H+O 2 combustion reaction and find that they are resonance dominated and rise linearly above threshold. The reaction probability is not enhanced by vibrational or rotational excitation of the reactants but does increase above the threshold for vibrationally excited products.

UR - http://www.scopus.com/inward/record.url?scp=0001124107&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001124107&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0001124107

VL - 99

SP - 9310

EP - 9313

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 11

ER -