Alcohol addition to acetonitrile activated by the [Re63-Se)8]2+ cluster core

Peter Orto, Hugh D. Selby, Daniel Ferris, Jenine R. Maeyer, Zhiping Zheng

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Abstract

The addition of methanol and ethanol to the previously reported cluster solvates [Re63-Se)8(PEt3) 5(MeCN)](SbF6)2 and trans-[Re 6-(μ3-Se)8(PEt3) 4(CH3CN)2][SbF6]2 afforded three cluster complexes with imino ester ligands: {Re 63-Se)8(PEt3) 5[HN=C(OCH3)-(CH3)]}(SbF6) 2, {Re63-Se)8(PEt 3)5[HN=C(OCH2CH3)(CH 3)]}-{SbF6}2, and trans-{Re63-Se)8(PEt3)4[HN=C(OCH 3)(CH3)]2}-{SbF6}2. In all cases, predominant formation of the Z isomers was observed.

Original languageEnglish (US)
Pages (from-to)4377-4379
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number11
DOIs
StatePublished - May 28 2007

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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