Alkali activation of copper mine tailings and low-calcium flash-furnace copper smelter slag

Saeed Ahmari, Krishna Parameswaran, Lianyang Zhang

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

This paper studies alkali activation of copper mine tailings (MT) and low-calcium flash-furnace copper smelter slag (SG), two major types of wastes from the mining industry. The effect of SG content, curing temperature, and curing time on the unconfined compressive strength (UCS) of the MT/SG-based geopolymer is investigated systematically. Scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy are also used to investigate the microstructure and elemental and phase composition of the MT/SG-based geopolymer. The results show that the addition of SG significantly improves the UCS and microstructure of the geopolymer. The improvement is mainly attributed to the high solubility of silica in the SG and the fine particle size of the SG. The inclusion of SG also leads to decrease of the optimum curing temperature (i.e., the temperature at the highest UCS) because of its higher reactivity than MT. In addition, the MT/SG-based geopolymer sets fast and gains a major portion of its ultimate strength within only 7 days. Based on the results, it can be concluded that the MT/SG-based geopolymer is a promising sustainable construction material for civil engineering applications.

Original languageEnglish (US)
Article number04014193
JournalJournal of Materials in Civil Engineering
Volume27
Issue number6
DOIs
StatePublished - Jun 1 2015

Fingerprint

Copper mines
Tailings
Alkalies
Slags
Copper
Calcium
Furnaces
Chemical activation
Geopolymers
Compressive strength
Curing
Microstructure
Mineral industry
Civil engineering
Phase composition
Silicon Dioxide
Temperature
Fourier transform infrared spectroscopy
Solubility
Particle size

Keywords

  • Flash-furnace copper smelter slag
  • Geoploymerization
  • Micro/nano-structure
  • Mine tailings
  • Unconfined compressive strength

ASJC Scopus subject areas

  • Civil and Structural Engineering
  • Building and Construction
  • Materials Science(all)
  • Mechanics of Materials

Cite this

Alkali activation of copper mine tailings and low-calcium flash-furnace copper smelter slag. / Ahmari, Saeed; Parameswaran, Krishna; Zhang, Lianyang.

In: Journal of Materials in Civil Engineering, Vol. 27, No. 6, 04014193, 01.06.2015.

Research output: Contribution to journalArticle

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