Allophane and imogolite

James Harsh, Jon Chorover, Egide Nizeyimana

Research output: Chapter in Book/Report/Conference proceedingChapter

20 Scopus citations

Abstract

Allophane and imogolite are poorly crystalline aluminosilicates characterized by small particle size, high specific surface area, and variable and/or permanent charge. Their high specific surface, unusual surface charge characteristics, and unique morphology lead to physical and chemical properties that can profoundly affect soil behavior. This chapter considers the environmental conditions under which these minerals form, their structural and surface characteristics, their effect on soil behavior, and their potential for beneficial use. Allophane and imogolite are responsible for the unique properties of soils derived from volcanic materials. Chemical composition is relatively stable in imogolite, but extremely variable in allophane, which may contain significant amounts of Fe in addition to Al and Si. The formation of allophane and imogolite is favored kinetically when dissolved Al and silica concentrations are between 0.1 and 4 mM.

Original languageEnglish (US)
Title of host publicationSoil Mineralogy with Environmental Applications
PublisherWiley-Blackwell
Pages291-322
Number of pages32
Volume7
ISBN (Electronic)9780891188919
ISBN (Print)9780891188391
DOIs
StatePublished - Sep 11 2018

Keywords

  • Allophane
  • Chemical composition
  • Chemical properties
  • Environmental conditions
  • Fibrous morphology
  • Imogolite
  • Mineral formation
  • Physical properties
  • Structural characteristics

ASJC Scopus subject areas

  • Engineering(all)
  • Agricultural and Biological Sciences(all)

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