Aluminous orthopyroxene

Order-disorder, thermodynamic properties, and petrologic implications

Jibamitra Ganguly, Subrata Ghose

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

Orthopyroxene has two tetrahedral sites, designated A and B, and two octahedral sites, M1 and M2. Crystallographic studies of synthetic and natural orthopyroxenes (opx) suggest that the tetrahedral Al is ordered nearly completely in the B site, but the octahedral Al disorders between M1 and M2 sites with a preference for M1. If the 'aluminum avoidance' principle is obeyed, then the tetrahedral Si-Al ordering limits the Al substitution in opx to 25 mol%, thus leading to an end-member stoichiometry of Mg3Al2Si3O12 instead of MgAl2SiO6. The enthalpy of formation of these two components has been deduced from the available phase equilibrium data. The thermodynamic properties of the opx solid solution approximates ideal solution behavior more closely when treated in terms of the components Mg4Si4O12(QEn)-Mg3Al2Si3O12(Py) than when expressed in terms of the components Mg2Si2O6-MgAl2SiO6. A model has been developed for the octahedral disordering of Al as function of temperature and composition. These data enable calculation of the configurational entropy and molar entropy of Al-opx; distinction has been made between the cases of completely random mixing of Al and Si in the tetrahedral B site, and of random mixing without violation of the 'aluminum avoidance' principle. The second model yields entropy of the Mg3Al2Si3O12 end member which agrees almost exactly with the value derived from phase equilibrium data. The partial molal entropies of the Orthopyroxene components 'QEn' and 'Py' can be derived from these data; their implications with respect to the P-T slopes of Al2O3 isopleths for the equilibrium of Orthopyroxene with forsterite and spinel/garnet have been discussed.

Original languageEnglish (US)
Pages (from-to)375-385
Number of pages11
JournalContributions to Mineralogy and Petrology
Volume69
Issue number4
DOIs
StatePublished - Aug 1979

Fingerprint

Order disorder transitions
thermodynamic property
orthopyroxene
crystal structure
entropy
Entropy
Thermodynamic properties
thermodynamic properties
disorders
avoidance
phase equilibrium
Aluminum
Phase equilibria
aluminum
nomographs
forsterite
Garnets
stoichiometry
enthalpy
solid solution

ASJC Scopus subject areas

  • Geophysics
  • Geochemistry and Petrology

Cite this

Aluminous orthopyroxene : Order-disorder, thermodynamic properties, and petrologic implications. / Ganguly, Jibamitra; Ghose, Subrata.

In: Contributions to Mineralogy and Petrology, Vol. 69, No. 4, 08.1979, p. 375-385.

Research output: Contribution to journalArticle

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abstract = "Orthopyroxene has two tetrahedral sites, designated A and B, and two octahedral sites, M1 and M2. Crystallographic studies of synthetic and natural orthopyroxenes (opx) suggest that the tetrahedral Al is ordered nearly completely in the B site, but the octahedral Al disorders between M1 and M2 sites with a preference for M1. If the 'aluminum avoidance' principle is obeyed, then the tetrahedral Si-Al ordering limits the Al substitution in opx to 25 mol{\%}, thus leading to an end-member stoichiometry of Mg3Al2Si3O12 instead of MgAl2SiO6. The enthalpy of formation of these two components has been deduced from the available phase equilibrium data. The thermodynamic properties of the opx solid solution approximates ideal solution behavior more closely when treated in terms of the components Mg4Si4O12(QEn)-Mg3Al2Si3O12(Py) than when expressed in terms of the components Mg2Si2O6-MgAl2SiO6. A model has been developed for the octahedral disordering of Al as function of temperature and composition. These data enable calculation of the configurational entropy and molar entropy of Al-opx; distinction has been made between the cases of completely random mixing of Al and Si in the tetrahedral B site, and of random mixing without violation of the 'aluminum avoidance' principle. The second model yields entropy of the Mg3Al2Si3O12 end member which agrees almost exactly with the value derived from phase equilibrium data. The partial molal entropies of the Orthopyroxene components 'QEn' and 'Py' can be derived from these data; their implications with respect to the P-T slopes of Al2O3 isopleths for the equilibrium of Orthopyroxene with forsterite and spinel/garnet have been discussed.",
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