An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet

Jiong Yang, Yi Fei Deng, Xin Yu Zhang, Xiao Yong Chang, Zhiping Zheng, Yuan Zhu Zhang

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni21,1-N3)2·(DMF)}{Tp∗Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.

Original languageEnglish (US)
Pages (from-to)7127-7130
Number of pages4
JournalInorganic Chemistry
Volume58
Issue number11
DOIs
StatePublished - Jun 3 2019
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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