An electrochemical and photophysical study of a covalently linked inorganic-organic dyad

Axel Kahnt, Leo Philipp Heiniger, Shi Xia Liu, Xiaoyan Tu, Zhiping Zheng, Andreas Hauser, Silvio Decurtins, Dirk M. Guldi

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A molecular donor-acceptor dyad comprising a hexarhenium cluster core, [Re6(m3-Se)8]2+, and a fullerene moiety which are covalently linked through a pyridine ligand was synthesized and fully characterized. The electrochemical and photophysical properties are reported. The detailed study includes cyclic voltammetry, steady-state absorption and fluorescence spectroscopy, radiation chemistry and transient absorption spectroscopy. A light-induced electron transfer between the inorganic cluster moiety and the fullerene can be excluded. However, a light-induced energy transfer from the rhenium cluster to the fullerene is proposed

Original languageEnglish (US)
Pages (from-to)651-658
Number of pages8
JournalChemPhysChem
Volume11
Issue number3
DOIs
StatePublished - Feb 22 2010

Fingerprint

Fullerenes
fullerenes
Absorption spectroscopy
absorption spectroscopy
Radiation chemistry
Rhenium
radiation chemistry
Fluorescence spectroscopy
rhenium
Energy transfer
Cyclic voltammetry
pyridines
electron transfer
energy transfer
Ligands
fluorescence
ligands
Electrons
spectroscopy

Keywords

  • Cluster compounds
  • Cyclic voltammetry
  • Energy transfer
  • Fullerenes radiation chemistry

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics

Cite this

Kahnt, A., Heiniger, L. P., Liu, S. X., Tu, X., Zheng, Z., Hauser, A., ... Guldi, D. M. (2010). An electrochemical and photophysical study of a covalently linked inorganic-organic dyad. ChemPhysChem, 11(3), 651-658. https://doi.org/10.1002/cphc.200900728

An electrochemical and photophysical study of a covalently linked inorganic-organic dyad. / Kahnt, Axel; Heiniger, Leo Philipp; Liu, Shi Xia; Tu, Xiaoyan; Zheng, Zhiping; Hauser, Andreas; Decurtins, Silvio; Guldi, Dirk M.

In: ChemPhysChem, Vol. 11, No. 3, 22.02.2010, p. 651-658.

Research output: Contribution to journalArticle

Kahnt, A, Heiniger, LP, Liu, SX, Tu, X, Zheng, Z, Hauser, A, Decurtins, S & Guldi, DM 2010, 'An electrochemical and photophysical study of a covalently linked inorganic-organic dyad', ChemPhysChem, vol. 11, no. 3, pp. 651-658. https://doi.org/10.1002/cphc.200900728
Kahnt, Axel ; Heiniger, Leo Philipp ; Liu, Shi Xia ; Tu, Xiaoyan ; Zheng, Zhiping ; Hauser, Andreas ; Decurtins, Silvio ; Guldi, Dirk M. / An electrochemical and photophysical study of a covalently linked inorganic-organic dyad. In: ChemPhysChem. 2010 ; Vol. 11, No. 3. pp. 651-658.
@article{4f24309cf8af4c04a4e8863e76e66751,
title = "An electrochemical and photophysical study of a covalently linked inorganic-organic dyad",
abstract = "A molecular donor-acceptor dyad comprising a hexarhenium cluster core, [Re6(m3-Se)8]2+, and a fullerene moiety which are covalently linked through a pyridine ligand was synthesized and fully characterized. The electrochemical and photophysical properties are reported. The detailed study includes cyclic voltammetry, steady-state absorption and fluorescence spectroscopy, radiation chemistry and transient absorption spectroscopy. A light-induced electron transfer between the inorganic cluster moiety and the fullerene can be excluded. However, a light-induced energy transfer from the rhenium cluster to the fullerene is proposed",
keywords = "Cluster compounds, Cyclic voltammetry, Energy transfer, Fullerenes radiation chemistry",
author = "Axel Kahnt and Heiniger, {Leo Philipp} and Liu, {Shi Xia} and Xiaoyan Tu and Zhiping Zheng and Andreas Hauser and Silvio Decurtins and Guldi, {Dirk M.}",
year = "2010",
month = "2",
day = "22",
doi = "10.1002/cphc.200900728",
language = "English (US)",
volume = "11",
pages = "651--658",
journal = "ChemPhysChem",
issn = "1439-4235",
publisher = "Wiley-VCH Verlag",
number = "3",

}

TY - JOUR

T1 - An electrochemical and photophysical study of a covalently linked inorganic-organic dyad

AU - Kahnt, Axel

AU - Heiniger, Leo Philipp

AU - Liu, Shi Xia

AU - Tu, Xiaoyan

AU - Zheng, Zhiping

AU - Hauser, Andreas

AU - Decurtins, Silvio

AU - Guldi, Dirk M.

PY - 2010/2/22

Y1 - 2010/2/22

N2 - A molecular donor-acceptor dyad comprising a hexarhenium cluster core, [Re6(m3-Se)8]2+, and a fullerene moiety which are covalently linked through a pyridine ligand was synthesized and fully characterized. The electrochemical and photophysical properties are reported. The detailed study includes cyclic voltammetry, steady-state absorption and fluorescence spectroscopy, radiation chemistry and transient absorption spectroscopy. A light-induced electron transfer between the inorganic cluster moiety and the fullerene can be excluded. However, a light-induced energy transfer from the rhenium cluster to the fullerene is proposed

AB - A molecular donor-acceptor dyad comprising a hexarhenium cluster core, [Re6(m3-Se)8]2+, and a fullerene moiety which are covalently linked through a pyridine ligand was synthesized and fully characterized. The electrochemical and photophysical properties are reported. The detailed study includes cyclic voltammetry, steady-state absorption and fluorescence spectroscopy, radiation chemistry and transient absorption spectroscopy. A light-induced electron transfer between the inorganic cluster moiety and the fullerene can be excluded. However, a light-induced energy transfer from the rhenium cluster to the fullerene is proposed

KW - Cluster compounds

KW - Cyclic voltammetry

KW - Energy transfer

KW - Fullerenes radiation chemistry

UR - http://www.scopus.com/inward/record.url?scp=77149127704&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77149127704&partnerID=8YFLogxK

U2 - 10.1002/cphc.200900728

DO - 10.1002/cphc.200900728

M3 - Article

VL - 11

SP - 651

EP - 658

JO - ChemPhysChem

JF - ChemPhysChem

SN - 1439-4235

IS - 3

ER -