Abstract
The cluster complex, [Re6(μ3-Se) 8(PEt3)5(4-vinylpyridine)](SbF 6)2 (1), featuring the face-capped octahedral [Re 6(μ3-Se)8]2+ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P21 with a = 11.748(1) Å, b = 15.1212(2) Å, c = 19.941(2) Å, α = 90°, β = 94.411(3)°, γ = 90°, V = 3531.8(7) Å3, Z = 2, R1 = 0.0531, wR2 = 0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 449-458 |
| Number of pages | 10 |
| Journal | Journal of Cluster Science |
| Volume | 14 |
| Issue number | 4 |
| DOIs | |
| State | Published - Dec 2003 |
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Keywords
- 4-vinylpyridine
- Organic-inorganic hybrid composites
- Polymerization
- Rhenium chalcogenide clusters
ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
An inorganic-organic hybrid composite featuring metal-chalcogenide clusters. / Roland, Bryan K.; Flora, Ware H.; Carducci, Michael D.; Armstrong, Neal R; Zheng, Zhiping.
In: Journal of Cluster Science, Vol. 14, No. 4, 12.2003, p. 449-458.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - An inorganic-organic hybrid composite featuring metal-chalcogenide clusters
AU - Roland, Bryan K.
AU - Flora, Ware H.
AU - Carducci, Michael D.
AU - Armstrong, Neal R
AU - Zheng, Zhiping
PY - 2003/12
Y1 - 2003/12
N2 - The cluster complex, [Re6(μ3-Se) 8(PEt3)5(4-vinylpyridine)](SbF 6)2 (1), featuring the face-capped octahedral [Re 6(μ3-Se)8]2+ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P21 with a = 11.748(1) Å, b = 15.1212(2) Å, c = 19.941(2) Å, α = 90°, β = 94.411(3)°, γ = 90°, V = 3531.8(7) Å3, Z = 2, R1 = 0.0531, wR2 = 0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.
AB - The cluster complex, [Re6(μ3-Se) 8(PEt3)5(4-vinylpyridine)](SbF 6)2 (1), featuring the face-capped octahedral [Re 6(μ3-Se)8]2+ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P21 with a = 11.748(1) Å, b = 15.1212(2) Å, c = 19.941(2) Å, α = 90°, β = 94.411(3)°, γ = 90°, V = 3531.8(7) Å3, Z = 2, R1 = 0.0531, wR2 = 0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.
KW - 4-vinylpyridine
KW - Organic-inorganic hybrid composites
KW - Polymerization
KW - Rhenium chalcogenide clusters
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UR - http://www.scopus.com/inward/citedby.url?scp=3543108983&partnerID=8YFLogxK
U2 - 10.1023/B:JOCL.0000010916.59703.98
DO - 10.1023/B:JOCL.0000010916.59703.98
M3 - Article
AN - SCOPUS:3543108983
VL - 14
SP - 449
EP - 458
JO - Journal of Cluster Science
JF - Journal of Cluster Science
SN - 1040-7278
IS - 4
ER -