Anorpiment, As 2S 3, the triclinic dimorph of orpiment

A. R. Kampf, Robert T Downs, R. M. Housley, R. A. Jenkins, J. Hyrsl

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The new mineral anorpiment, As 2S 3, the triclinic dimorph of orpiment, has space group P1 and cell parameters a = 5.7577(2), b = 8.7169(3), c = 10.2682(7) Å, α = 78.152(7), β = 75.817(7), γ = 89.861(6)°, V = 488.38(4) Å 3 and Z = 4. It occurs at the Palomo mine, Castrovirreyna Province, Huancavelica Department, Peru. It is a low-temperature hydrothermal mineral associated with dufrénoysite, muscovite, orpiment, pyrite and realgar. It occurs in drusy crusts of wedge-shaped, transparent, greenish yellow crystals. The streak is yellow. The lustre is resinous on crystal faces, but pearly on cleavage surfaces. The Mohs hardness is about 1½. The mineral is sectile with an irregular fracture and one perfect and easy cleavage on {001}. The measured and calculated densities are 3.33 and 3.321 g cm -3, respectively. All indices of refraction are greater than 2. The mineral is optically biaxial (-) with 2V = 35-40° and no observed dispersion. The acute bisectrix (X) is approximately perpendicular to the {001} cleavage. Electron microprobe analyses yielded the averages and ranges in wt.%: As 58.21 (57.74-59.03), S 38.72 (38.33-39.00), total 96.94 (96.07-97.75), providing the empirical formula (based on 5 atoms) As 1.96S 3.04. The strongest powder X-ray diffraction lines are [d (hkl) I] 4.867(002) 97, 4.519 (110,111) 77, 3.702 (111) 46, 3.609 (022,112) 82, 2.880 (201,022,121,023) 75, 2.552 (113,131,132) 100, 2.469 (114,130,131) 96. The structure of anorpiment [R 1 = 0.021 for1484 reflections with F o > 4σ(F)] consists of layers of covalently bonded As and S atoms. Each S atom bonds to two As atoms at As-S-As angles between 100.45 and 104.15°. Each As atom is strongly bonded to three S atoms at S-As-S angles between 91.28 and 103.59°, forming an AsS 3 pyramid with As at its apex. The As-S linkages within the layers form rings of six AsS 3 pyramids. Interlayer bonding forces are interpreted as van der Waals. The structure of anorpiment is similar to that of orpiment in that it is composed of layers of As 2S 3 macromolecules, but arranged in a different stacking sequence.

Original languageEnglish (US)
Pages (from-to)2857-2867
Number of pages11
JournalMineralogical Magazine
Volume75
Issue number6
DOIs
StatePublished - 2011

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cleavage
Atoms
Minerals
mineral
realgar
crystal
new mineral
refraction
stacking
muscovite
electron probe analysis
hardness
pyrite
X-ray diffraction
crust
Crystals
Refraction
Macromolecules
X ray powder diffraction
arsenic trisulfide

Keywords

  • anorpiment
  • arsenic sulphide
  • crystal structure
  • new mineral
  • orpiment
  • Palomo mine
  • Peru
  • van der Waals forces

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

Anorpiment, As 2S 3, the triclinic dimorph of orpiment. / Kampf, A. R.; Downs, Robert T; Housley, R. M.; Jenkins, R. A.; Hyrsl, J.

In: Mineralogical Magazine, Vol. 75, No. 6, 2011, p. 2857-2867.

Research output: Contribution to journalArticle

Kampf, AR, Downs, RT, Housley, RM, Jenkins, RA & Hyrsl, J 2011, 'Anorpiment, As 2S 3, the triclinic dimorph of orpiment', Mineralogical Magazine, vol. 75, no. 6, pp. 2857-2867. https://doi.org/10.1180/minmag.2011.075.6.2857
Kampf, A. R. ; Downs, Robert T ; Housley, R. M. ; Jenkins, R. A. ; Hyrsl, J. / Anorpiment, As 2S 3, the triclinic dimorph of orpiment. In: Mineralogical Magazine. 2011 ; Vol. 75, No. 6. pp. 2857-2867.
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abstract = "The new mineral anorpiment, As 2S 3, the triclinic dimorph of orpiment, has space group P1 and cell parameters a = 5.7577(2), b = 8.7169(3), c = 10.2682(7) {\AA}, α = 78.152(7), β = 75.817(7), γ = 89.861(6)°, V = 488.38(4) {\AA} 3 and Z = 4. It occurs at the Palomo mine, Castrovirreyna Province, Huancavelica Department, Peru. It is a low-temperature hydrothermal mineral associated with dufr{\'e}noysite, muscovite, orpiment, pyrite and realgar. It occurs in drusy crusts of wedge-shaped, transparent, greenish yellow crystals. The streak is yellow. The lustre is resinous on crystal faces, but pearly on cleavage surfaces. The Mohs hardness is about 1½. The mineral is sectile with an irregular fracture and one perfect and easy cleavage on {001}. The measured and calculated densities are 3.33 and 3.321 g cm -3, respectively. All indices of refraction are greater than 2. The mineral is optically biaxial (-) with 2V = 35-40° and no observed dispersion. The acute bisectrix (X) is approximately perpendicular to the {001} cleavage. Electron microprobe analyses yielded the averages and ranges in wt.{\%}: As 58.21 (57.74-59.03), S 38.72 (38.33-39.00), total 96.94 (96.07-97.75), providing the empirical formula (based on 5 atoms) As 1.96S 3.04. The strongest powder X-ray diffraction lines are [d (hkl) I] 4.867(002) 97, 4.519 (110,111) 77, 3.702 (111) 46, 3.609 (022,112) 82, 2.880 (201,022,121,023) 75, 2.552 (113,131,132) 100, 2.469 (114,130,131) 96. The structure of anorpiment [R 1 = 0.021 for1484 reflections with F o > 4σ(F)] consists of layers of covalently bonded As and S atoms. Each S atom bonds to two As atoms at As-S-As angles between 100.45 and 104.15°. Each As atom is strongly bonded to three S atoms at S-As-S angles between 91.28 and 103.59°, forming an AsS 3 pyramid with As at its apex. The As-S linkages within the layers form rings of six AsS 3 pyramids. Interlayer bonding forces are interpreted as van der Waals. The structure of anorpiment is similar to that of orpiment in that it is composed of layers of As 2S 3 macromolecules, but arranged in a different stacking sequence.",
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TY - JOUR

T1 - Anorpiment, As 2S 3, the triclinic dimorph of orpiment

AU - Kampf, A. R.

AU - Downs, Robert T

AU - Housley, R. M.

AU - Jenkins, R. A.

AU - Hyrsl, J.

PY - 2011

Y1 - 2011

N2 - The new mineral anorpiment, As 2S 3, the triclinic dimorph of orpiment, has space group P1 and cell parameters a = 5.7577(2), b = 8.7169(3), c = 10.2682(7) Å, α = 78.152(7), β = 75.817(7), γ = 89.861(6)°, V = 488.38(4) Å 3 and Z = 4. It occurs at the Palomo mine, Castrovirreyna Province, Huancavelica Department, Peru. It is a low-temperature hydrothermal mineral associated with dufrénoysite, muscovite, orpiment, pyrite and realgar. It occurs in drusy crusts of wedge-shaped, transparent, greenish yellow crystals. The streak is yellow. The lustre is resinous on crystal faces, but pearly on cleavage surfaces. The Mohs hardness is about 1½. The mineral is sectile with an irregular fracture and one perfect and easy cleavage on {001}. The measured and calculated densities are 3.33 and 3.321 g cm -3, respectively. All indices of refraction are greater than 2. The mineral is optically biaxial (-) with 2V = 35-40° and no observed dispersion. The acute bisectrix (X) is approximately perpendicular to the {001} cleavage. Electron microprobe analyses yielded the averages and ranges in wt.%: As 58.21 (57.74-59.03), S 38.72 (38.33-39.00), total 96.94 (96.07-97.75), providing the empirical formula (based on 5 atoms) As 1.96S 3.04. The strongest powder X-ray diffraction lines are [d (hkl) I] 4.867(002) 97, 4.519 (110,111) 77, 3.702 (111) 46, 3.609 (022,112) 82, 2.880 (201,022,121,023) 75, 2.552 (113,131,132) 100, 2.469 (114,130,131) 96. The structure of anorpiment [R 1 = 0.021 for1484 reflections with F o > 4σ(F)] consists of layers of covalently bonded As and S atoms. Each S atom bonds to two As atoms at As-S-As angles between 100.45 and 104.15°. Each As atom is strongly bonded to three S atoms at S-As-S angles between 91.28 and 103.59°, forming an AsS 3 pyramid with As at its apex. The As-S linkages within the layers form rings of six AsS 3 pyramids. Interlayer bonding forces are interpreted as van der Waals. The structure of anorpiment is similar to that of orpiment in that it is composed of layers of As 2S 3 macromolecules, but arranged in a different stacking sequence.

AB - The new mineral anorpiment, As 2S 3, the triclinic dimorph of orpiment, has space group P1 and cell parameters a = 5.7577(2), b = 8.7169(3), c = 10.2682(7) Å, α = 78.152(7), β = 75.817(7), γ = 89.861(6)°, V = 488.38(4) Å 3 and Z = 4. It occurs at the Palomo mine, Castrovirreyna Province, Huancavelica Department, Peru. It is a low-temperature hydrothermal mineral associated with dufrénoysite, muscovite, orpiment, pyrite and realgar. It occurs in drusy crusts of wedge-shaped, transparent, greenish yellow crystals. The streak is yellow. The lustre is resinous on crystal faces, but pearly on cleavage surfaces. The Mohs hardness is about 1½. The mineral is sectile with an irregular fracture and one perfect and easy cleavage on {001}. The measured and calculated densities are 3.33 and 3.321 g cm -3, respectively. All indices of refraction are greater than 2. The mineral is optically biaxial (-) with 2V = 35-40° and no observed dispersion. The acute bisectrix (X) is approximately perpendicular to the {001} cleavage. Electron microprobe analyses yielded the averages and ranges in wt.%: As 58.21 (57.74-59.03), S 38.72 (38.33-39.00), total 96.94 (96.07-97.75), providing the empirical formula (based on 5 atoms) As 1.96S 3.04. The strongest powder X-ray diffraction lines are [d (hkl) I] 4.867(002) 97, 4.519 (110,111) 77, 3.702 (111) 46, 3.609 (022,112) 82, 2.880 (201,022,121,023) 75, 2.552 (113,131,132) 100, 2.469 (114,130,131) 96. The structure of anorpiment [R 1 = 0.021 for1484 reflections with F o > 4σ(F)] consists of layers of covalently bonded As and S atoms. Each S atom bonds to two As atoms at As-S-As angles between 100.45 and 104.15°. Each As atom is strongly bonded to three S atoms at S-As-S angles between 91.28 and 103.59°, forming an AsS 3 pyramid with As at its apex. The As-S linkages within the layers form rings of six AsS 3 pyramids. Interlayer bonding forces are interpreted as van der Waals. The structure of anorpiment is similar to that of orpiment in that it is composed of layers of As 2S 3 macromolecules, but arranged in a different stacking sequence.

KW - anorpiment

KW - arsenic sulphide

KW - crystal structure

KW - new mineral

KW - orpiment

KW - Palomo mine

KW - Peru

KW - van der Waals forces

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