Arylene- and Alkylene-Bridged Siliconates

Douglas A. Loy, James H. Small, Kenneth J. Shea

Research output: Contribution to journalComment/debate

15 Scopus citations

Abstract

Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

Original languageEnglish (US)
Pages (from-to)1484-1488
Number of pages5
JournalOrganometallics
Volume12
Issue number4
DOIs
StatePublished - Jan 1 1993
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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