Assessing the current state of commercially available membranes and spacers for energy production with pressure retarded osmosis

Kerri L. Hickenbottom, Johan Vanneste, Menachem Elimelech, Tzahi Y. Cath

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Pressure retarded osmosis (PRO) is an osmotically driven membrane process that utilizes the energy of mixing between streams of high and low chemical potential to generate electrical energy. High power density of a PRO membrane is essential to maximize process efficiency and minimize the capital and operating costs. Thus, robust PRO membranes that can support high pressure and have high water flux, low reverse salt flux, low structural parameter, and a good membrane support structure are needed. In this study, four commercial forward osmosis (FO) membranes for use in PRO were compared. The effect of operating pressures, membrane spacers (type, orientation, and arrangement), and flow velocities on process performance were investigated. A thin film composite polyamide membrane from Hydration Technology Innovations was found to be the most robust and selective membrane. Compared to other spacer configurations, the use of unique feed channel spacer orientations was found to increase PRO power density by up to 46%, yielding a power density of 22.6 W/m2 (3 M NaCl draw solution and 4.1 MPa hydraulic pressure). However, membrane deformation was observed when operating pressures exceeded 3.5 MPa. The use of unique spacers coupled with decreased draw solution cross-flow velocities was found to increase PRO process efficiency.

Original languageEnglish (US)
Pages (from-to)108-118
Number of pages11
JournalDesalination
Volume389
DOIs
StatePublished - Jul 1 2016
Externally publishedYes

Fingerprint

Osmosis
osmosis
membrane
Membranes
Osmosis membranes
flow velocity
Flow velocity
energy production
support structure
Fluxes
Chemical potential
Nylons
hydration
Polyamides
Operating costs
energy
Hydration
innovation
Salts
Innovation

Keywords

  • Energy-water nexus
  • Membrane integrity
  • Osmotic power
  • Power density
  • Pressure retarded osmosis

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Science(all)
  • Water Science and Technology
  • Mechanical Engineering

Cite this

Assessing the current state of commercially available membranes and spacers for energy production with pressure retarded osmosis. / Hickenbottom, Kerri L.; Vanneste, Johan; Elimelech, Menachem; Cath, Tzahi Y.

In: Desalination, Vol. 389, 01.07.2016, p. 108-118.

Research output: Contribution to journalArticle

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