Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

Luciano Cuesta, Elisa Tomat, Vincent M. Lynch, Jonathan L. Sessler

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Abstract

The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an η2-fashion.

Original languageEnglish (US)
Pages (from-to)3744-3746
Number of pages3
JournalChemical Communications
Issue number32
DOIs
Publication statusPublished - 2008
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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