Bonding in the heavy analogue of hydrogen cyanide: The curious case of bridged HPSi

Valerio Lattanzi, Sven Thorwirth, DeWayne T. Halfen, Leonie Anna Mück, Lucy M Ziurys, Patrick Thaddeus, Jürgen Gauss, Michael C. McCarthy

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

chemical equation presented Curiouser and curiouser: By combining high-resolution molecular spectroscopy in the centimeter and millimeter wave regions, and high-level coupled-cluster quantum-chemical calculations, the structure of the HPSi molecule has been determined. The bridged geometry of HPSi is in remarkable contrast to that of the C and/or N analogues, such as HCN/ HNC, HCP, and HNSi, which are all linear.

Original languageEnglish (US)
Pages (from-to)5661-5664
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number33
DOIs
StatePublished - Aug 2 2010

Fingerprint

Hydrogen Cyanide
Cyanides
Molecular spectroscopy
Hydrogen
Millimeter waves
Molecules
Geometry

Keywords

  • Multiple bonds
  • Phosphorous
  • Quantum-chemical calculations
  • Rotational spectroscopy
  • Silicon

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Lattanzi, V., Thorwirth, S., Halfen, D. T., Mück, L. A., Ziurys, L. M., Thaddeus, P., ... McCarthy, M. C. (2010). Bonding in the heavy analogue of hydrogen cyanide: The curious case of bridged HPSi. Angewandte Chemie - International Edition, 49(33), 5661-5664. https://doi.org/10.1002/anie.201001938

Bonding in the heavy analogue of hydrogen cyanide : The curious case of bridged HPSi. / Lattanzi, Valerio; Thorwirth, Sven; Halfen, DeWayne T.; Mück, Leonie Anna; Ziurys, Lucy M; Thaddeus, Patrick; Gauss, Jürgen; McCarthy, Michael C.

In: Angewandte Chemie - International Edition, Vol. 49, No. 33, 02.08.2010, p. 5661-5664.

Research output: Contribution to journalArticle

Lattanzi, V, Thorwirth, S, Halfen, DT, Mück, LA, Ziurys, LM, Thaddeus, P, Gauss, J & McCarthy, MC 2010, 'Bonding in the heavy analogue of hydrogen cyanide: The curious case of bridged HPSi', Angewandte Chemie - International Edition, vol. 49, no. 33, pp. 5661-5664. https://doi.org/10.1002/anie.201001938
Lattanzi, Valerio ; Thorwirth, Sven ; Halfen, DeWayne T. ; Mück, Leonie Anna ; Ziurys, Lucy M ; Thaddeus, Patrick ; Gauss, Jürgen ; McCarthy, Michael C. / Bonding in the heavy analogue of hydrogen cyanide : The curious case of bridged HPSi. In: Angewandte Chemie - International Edition. 2010 ; Vol. 49, No. 33. pp. 5661-5664.
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