Characterization of performance and wear mechanism of diamond electrodes used for electrochemical oxidation of TCE

Brian P. Chaplin, James Farrell, John Carlisle, Hongjun Zeng

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Boron-doped diamond (BDD) electrodes have shown tremendous promise for the oxidation of recalcitrant and complex waste streams through a combination of direct electron transfer at the electrode surface and indirect electron transfer mediated by hydroxyl radicals produced by water oxidation. However, little research has been dedicated to understanding the mechanisms associated with electrode wear and the effects of electrode wear on the mechanisms (direct vs. indirect) of contaminant oxidation. In this work, TCE is used as a model organic contaminant to investigate the relationship between electrode wear and the mechanisms of contaminant oxidation. Surface characterization (XPS, SEM, AFM) of the electrodes along with electrochemical impedance spectroscopy are used to correlate the electrode structure with measured TCE oxidation rates. This information will help to obtain a better understanding of the mechanisms associated with BDD electrode wear and will aid in the design of long-life electrodes.

Original languageEnglish (US)
Title of host publicationACS National Meeting Book of Abstracts
Publication statusPublished - 2010
Event240th ACS National Meeting and Exposition - Boston, MA, United States
Duration: Aug 22 2010Aug 26 2010

Other

Other240th ACS National Meeting and Exposition
CountryUnited States
CityBoston, MA
Period8/22/108/26/10

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ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Chaplin, B. P., Farrell, J., Carlisle, J., & Zeng, H. (2010). Characterization of performance and wear mechanism of diamond electrodes used for electrochemical oxidation of TCE. In ACS National Meeting Book of Abstracts