Characterization of poly(xylylenes) with solid-state 13C nuclear magnetic resonance spectroscopy

Douglas A Loy, Roger A. Assink, Gregory M. Jamison, W. Frere McNamara, S. Prabakar, Duane A. Schneider

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Poly(xylylenes) are an important class of thermoplastics that are readily prepared by thermolysis of [2.2]paracyclophane or xylene precursors to afford xylylene monomers that condense and polymerize on solid surfaces to give polymer films. As most poly(xylylenes) are insoluble due to a high degree of crystallinity, characterization by solid-state nuclear magnetic resonance spectroscopic techniques is necessary. In this paper we describe the preparation of poly(xylylene) (P1), poly(2-ethylxylylene) (P2), poly(2-chloroxylylene) (P3), poly(2,3-dichloroxylylene) (P4), and poly(α,α,α′,α′-tetrafluoroxylylene) (P5) and their characterization using solid-state 13C cross polarization magic angle spinning nuclear magnetic resonance (CP MAS NMR) spectroscopy.

Original languageEnglish (US)
Pages (from-to)5799-5803
Number of pages5
JournalMacromolecules
Volume28
Issue number17
StatePublished - Jan 1 1995
Externally publishedYes

Fingerprint

Nuclear magnetic resonance spectroscopy
Xylenes
Thermolysis
Magic angle spinning
Xylene
Polymer films
Thermoplastics
Monomers
Nuclear magnetic resonance
Polarization
(2.2)paracyclophane

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Loy, D. A., Assink, R. A., Jamison, G. M., McNamara, W. F., Prabakar, S., & Schneider, D. A. (1995). Characterization of poly(xylylenes) with solid-state 13C nuclear magnetic resonance spectroscopy. Macromolecules, 28(17), 5799-5803.

Characterization of poly(xylylenes) with solid-state 13C nuclear magnetic resonance spectroscopy. / Loy, Douglas A; Assink, Roger A.; Jamison, Gregory M.; McNamara, W. Frere; Prabakar, S.; Schneider, Duane A.

In: Macromolecules, Vol. 28, No. 17, 01.01.1995, p. 5799-5803.

Research output: Contribution to journalArticle

Loy, DA, Assink, RA, Jamison, GM, McNamara, WF, Prabakar, S & Schneider, DA 1995, 'Characterization of poly(xylylenes) with solid-state 13C nuclear magnetic resonance spectroscopy', Macromolecules, vol. 28, no. 17, pp. 5799-5803.
Loy DA, Assink RA, Jamison GM, McNamara WF, Prabakar S, Schneider DA. Characterization of poly(xylylenes) with solid-state 13C nuclear magnetic resonance spectroscopy. Macromolecules. 1995 Jan 1;28(17):5799-5803.
Loy, Douglas A ; Assink, Roger A. ; Jamison, Gregory M. ; McNamara, W. Frere ; Prabakar, S. ; Schneider, Duane A. / Characterization of poly(xylylenes) with solid-state 13C nuclear magnetic resonance spectroscopy. In: Macromolecules. 1995 ; Vol. 28, No. 17. pp. 5799-5803.
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