Chemistry of ylids. X. Diphenylsulfonium alkylides - A stereoselective synthesis of epoxides

A. William Johnson, Victor J. Hruby, Joseph L. Williams

Research output: Research - peer-reviewArticle

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Abstract

The preparation and properties of diphenylsulfonium benzylide (8) and butylide (9) are described. Both ylids can be dissociated into carbenes and phenyl sulfide. The benzylide 8 reacts stereoselectively with benzaldehydes to form trans-stilbene oxides.

LanguageEnglish (US)
Pages918-922
Number of pages5
JournalJournal of the American Chemical Society
Volume86
Issue number5
StatePublished - 1964
Externally publishedYes

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Benzaldehydes
Epoxy Compounds
Sulfides
stilbene oxide
carbene
Oxides

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Chemistry of ylids. X. Diphenylsulfonium alkylides - A stereoselective synthesis of epoxides. / William Johnson, A.; Hruby, Victor J.; Williams, Joseph L.

In: Journal of the American Chemical Society, Vol. 86, No. 5, 1964, p. 918-922.

Research output: Research - peer-reviewArticle

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