Cluster anions: Structure, interactions, and dynamics in the sub-nanoscale regime

Andrei Sanov, W. Carl Lineberger

Research output: Contribution to journalArticle

51 Scopus citations

Abstract

This article reflects on several recent advances in the studies of structure and dynamics of cluster anions, both as unique species and as a conceptual bridge between isolated molecules and the condensed phase. Applications involving photofragment and photodetachment spectroscopy, as well as femtosecond time-resolved experiments, are described. Special emphasis is given to the effects of microscopic solvation on the electronic structure and reactivity of negative ions in heterogeneous and homogeneous cluster environments. Several recent breakthroughs in experimental methodology are outlined, in particular the application of photoelectron imaging to the studies of molecular cluster anions.

Original languageEnglish (US)
Pages (from-to)2018-2032
Number of pages15
JournalPhysical Chemistry Chemical Physics
Volume6
Issue number9
DOIs
StatePublished - May 7 2004

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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