Colloidal polymerization of polymer-coated ferromagnetic nanoparticles into cobalt oxide nanowires

Pei Yuin Keng, Bo Yun Kim, In Bo Shim, Rabindra Sahoo, Peter E. Veneman, Neal R. Armstrong, Heemin Yoo, Jeanne E. Pemberton, Mathew M. Bull, Jared J. Griebel, Erin L. Ratcliff, Kenneth G. Nebesny, Jeffrey Pyun

Research output: Contribution to journalArticle

137 Scopus citations

Abstract

The preparation of polystyrene-coated cobalt oxide nanowires is reported via the colloidal polymerization of polymer-coated ferromagnetic cobalt nanoparticles (PS-CoNPs). Using a combination of dipolar nanoparticle assembly and a solution oxidation of preorganized metallic colloids, interconnected nanoparticles of cobalt oxide spanning micrometers in length were prepared. The colloidal polymerization of PS-CoNPs into cobalt oxide (CoO and Co 3O4) nanowires was achieved by bubbling O2 into PS-CoNP dispersions in 1,2-dichlorobenzene at 175 °C. Calcination of thin films of PS-coated cobalt oxide nanowires afforded Co3O4 metal oxide materials. Transmission electron microscopy (TEM) revealed the formation of interconnected nanoparticles of cobalt oxide with hollow inclusions, arising from a combination of dipolar assembly of PS-CoNPs and the nanoscale Kirkendall effect in the oxidation reaction. Using a wide range of spectroscopic and electrochemical characterization techniques, we demonstrate that cobalt oxide nanowires prepared via this novel methodology were electroactive with potential applications as nanostructured electrodes for energy storage.

Original languageEnglish (US)
Pages (from-to)3143-3157
Number of pages15
JournalACS Nano
Volume3
Issue number10
DOIs
StatePublished - Oct 27 2009

Keywords

  • CoO nanowires
  • Cobalt nanoparticles
  • Cobalt oxide nanowires
  • Dipolar assembly
  • Electrochemistry
  • Ferromagnetic nanoparticles
  • Magnetic assembly
  • Magnetic nanoparticles
  • Photoelectron spectroscopy
  • Raman spectroscopy

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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  • Cite this

    Keng, P. Y., Kim, B. Y., Shim, I. B., Sahoo, R., Veneman, P. E., Armstrong, N. R., Yoo, H., Pemberton, J. E., Bull, M. M., Griebel, J. J., Ratcliff, E. L., Nebesny, K. G., & Pyun, J. (2009). Colloidal polymerization of polymer-coated ferromagnetic nanoparticles into cobalt oxide nanowires. ACS Nano, 3(10), 3143-3157. https://doi.org/10.1021/nn900483w