Comparisons between a thin-film catalyzed microreactor and conventional lab reactors for PrOx kinetic studies

X. Ouyang, L. Bednarova, H. Chen, Stanley K H Pau, N. Lawal, W. Y. Lee, R. S. Besser

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

In our study of CO preferential oxidation (PrOx) on Pt/Al 2O 3 with a thin-film catalyzed microreactor, systematic differences of kinetic study results and characteristic curves of CO conversion were identified between the microreactor and conventional minimized packed-bed lab reactors (m-PBR's). Evidence suggested that the difference in heat transport limitations is the origin of these differences. In this paper, these differences were examined systematically. First, based on existing criteria for mass and heat transport limitations, we found negligible mass transport resistance for both types of reactors within typical PrOx operating conditions, but strong heat transport limitations for m-PBR's. Further, a non-isothermal reactor model was built to quantitatively study the effect of the heat transport limitations on PrOx reaction behavior. Model results showed that the temperature gradients in m-PBR's favor the r-WGS reaction, thus causing a much narrower range of permissible operating temperature compared to the microreactor. Accordingly, a more direct access to PrOx reaction kinetics is permitted by the microreactor because of its excellent heat transfer efficiency.

Original languageEnglish (US)
Title of host publication2005 AIChE Spring National Meeting, Conference Proceedings
Pages2917-2926
Number of pages10
StatePublished - 2005
Externally publishedYes
Event2005 AIChE Spring National Meeting - Atlanta, GA, United States
Duration: Apr 10 2005Apr 14 2005

Other

Other2005 AIChE Spring National Meeting
CountryUnited States
CityAtlanta, GA
Period4/10/054/14/05

Fingerprint

Packed beds
Thin films
Oxidation
Kinetics
Reaction kinetics
Thermal gradients
Mass transfer
Heat transfer
Hot Temperature
Temperature

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Ouyang, X., Bednarova, L., Chen, H., Pau, S. K. H., Lawal, N., Lee, W. Y., & Besser, R. S. (2005). Comparisons between a thin-film catalyzed microreactor and conventional lab reactors for PrOx kinetic studies. In 2005 AIChE Spring National Meeting, Conference Proceedings (pp. 2917-2926). [134f]

Comparisons between a thin-film catalyzed microreactor and conventional lab reactors for PrOx kinetic studies. / Ouyang, X.; Bednarova, L.; Chen, H.; Pau, Stanley K H; Lawal, N.; Lee, W. Y.; Besser, R. S.

2005 AIChE Spring National Meeting, Conference Proceedings. 2005. p. 2917-2926 134f.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Ouyang, X, Bednarova, L, Chen, H, Pau, SKH, Lawal, N, Lee, WY & Besser, RS 2005, Comparisons between a thin-film catalyzed microreactor and conventional lab reactors for PrOx kinetic studies. in 2005 AIChE Spring National Meeting, Conference Proceedings., 134f, pp. 2917-2926, 2005 AIChE Spring National Meeting, Atlanta, GA, United States, 4/10/05.
Ouyang X, Bednarova L, Chen H, Pau SKH, Lawal N, Lee WY et al. Comparisons between a thin-film catalyzed microreactor and conventional lab reactors for PrOx kinetic studies. In 2005 AIChE Spring National Meeting, Conference Proceedings. 2005. p. 2917-2926. 134f
Ouyang, X. ; Bednarova, L. ; Chen, H. ; Pau, Stanley K H ; Lawal, N. ; Lee, W. Y. ; Besser, R. S. / Comparisons between a thin-film catalyzed microreactor and conventional lab reactors for PrOx kinetic studies. 2005 AIChE Spring National Meeting, Conference Proceedings. 2005. pp. 2917-2926
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