Concentrations of select dissolved trace elements and anthropogenic organic compounds in the Mississippi River and major tributaries during the summer of 2012 and 2013

Derek D. Bussan, Clifford A. Ochs, Colin R. Jackson, Tarun Anumol, Shane A. Snyder, James V. Cizdziel

Research output: Research - peer-reviewArticle

  • 1 Citations

Abstract

The Mississippi River drainage basin includes the Illinois, Missouri, Ohio, Tennessee, and Arkansas rivers. These rivers drain areas with different physiography, population centers, and land use, with each contributing a different suites of metals and wastewater contaminants that can affect water quality. In July 2012, we determined 18 elements (Be, Rb, Sr, Cd, Cs, Ba, Tl, Pb, Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn) and chlorophyll-a (Chl-a) in the five major tributaries and in the Upper Mississippi River. The following summer, we determined both trace elements and 25 trace organic compounds at 10 sites in a longitudinal study of the main stem of the Mississippi River from Grafton, Illinois to Natchez, Mississippi. We detected wastewater contaminants, including pharmaceuticals and endocrine disrupting compounds, throughout the river system, with the highest concentrations occurring near urban centers (St. Louis and Memphis). Concentrations were highest for atrazine (673 ng L−1), DEET (540 ng L−1), TCPP (231 ng L−1), and caffeine (202 ng L−1). The Illinois, Missouri, and Yazoo rivers, which drain areas with intense agriculture, had relatively high concentrations of Chl-a and atrazine. However, the Ohio River delivered higher loads of contaminants to the Mississippi River, including an estimated 177 kg day−1 of atrazine, due to higher flow volumes. Concentrations of heavy metals (Ni, V, Co, Cu, Cd, and Zn) were relatively high in the Illinois River and low in the Ohio River, although dissolved metal concentrations were below US EPA maximum contaminant levels for surface water. Multivariate analysis demonstrated that the rivers can be distinguished based on elemental and contaminant profiles.

LanguageEnglish (US)
Article number73
JournalEnvironmental Monitoring and Assessment
Volume189
Issue number2
DOIs
StatePublished - Feb 1 2017

Fingerprint

tributary
organic compound
trace element
summer
river
Trace elements
Organic compounds
Rivers
pollutant
Impurities
atrazine
Herbicides
drain
chlorophyll a
wastewater
metal
Chlorophyll
Wastewater
Metals
multivariate analysis

Keywords

  • Atrazine
  • Chlorophyll-a
  • Mississippi River
  • Trace elements
  • Trace organic compounds

ASJC Scopus subject areas

  • Environmental Science(all)
  • Pollution
  • Management, Monitoring, Policy and Law

Cite this

Concentrations of select dissolved trace elements and anthropogenic organic compounds in the Mississippi River and major tributaries during the summer of 2012 and 2013. / Bussan, Derek D.; Ochs, Clifford A.; Jackson, Colin R.; Anumol, Tarun; Snyder, Shane A.; Cizdziel, James V.

In: Environmental Monitoring and Assessment, Vol. 189, No. 2, 73, 01.02.2017.

Research output: Research - peer-reviewArticle

@article{3a9ff5d1aa2f461dacaeba9ea1d3920f,
title = "Concentrations of select dissolved trace elements and anthropogenic organic compounds in the Mississippi River and major tributaries during the summer of 2012 and 2013",
abstract = "The Mississippi River drainage basin includes the Illinois, Missouri, Ohio, Tennessee, and Arkansas rivers. These rivers drain areas with different physiography, population centers, and land use, with each contributing a different suites of metals and wastewater contaminants that can affect water quality. In July 2012, we determined 18 elements (Be, Rb, Sr, Cd, Cs, Ba, Tl, Pb, Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn) and chlorophyll-a (Chl-a) in the five major tributaries and in the Upper Mississippi River. The following summer, we determined both trace elements and 25 trace organic compounds at 10 sites in a longitudinal study of the main stem of the Mississippi River from Grafton, Illinois to Natchez, Mississippi. We detected wastewater contaminants, including pharmaceuticals and endocrine disrupting compounds, throughout the river system, with the highest concentrations occurring near urban centers (St. Louis and Memphis). Concentrations were highest for atrazine (673 ng L−1), DEET (540 ng L−1), TCPP (231 ng L−1), and caffeine (202 ng L−1). The Illinois, Missouri, and Yazoo rivers, which drain areas with intense agriculture, had relatively high concentrations of Chl-a and atrazine. However, the Ohio River delivered higher loads of contaminants to the Mississippi River, including an estimated 177 kg day−1 of atrazine, due to higher flow volumes. Concentrations of heavy metals (Ni, V, Co, Cu, Cd, and Zn) were relatively high in the Illinois River and low in the Ohio River, although dissolved metal concentrations were below US EPA maximum contaminant levels for surface water. Multivariate analysis demonstrated that the rivers can be distinguished based on elemental and contaminant profiles.",
keywords = "Atrazine, Chlorophyll-a, Mississippi River, Trace elements, Trace organic compounds",
author = "Bussan, {Derek D.} and Ochs, {Clifford A.} and Jackson, {Colin R.} and Tarun Anumol and Snyder, {Shane A.} and Cizdziel, {James V.}",
year = "2017",
month = "2",
doi = "10.1007/s10661-017-5785-x",
volume = "189",
journal = "Environmental Monitoring and Assessment",
issn = "0167-6369",
publisher = "Springer Netherlands",
number = "2",

}

TY - JOUR

T1 - Concentrations of select dissolved trace elements and anthropogenic organic compounds in the Mississippi River and major tributaries during the summer of 2012 and 2013

AU - Bussan,Derek D.

AU - Ochs,Clifford A.

AU - Jackson,Colin R.

AU - Anumol,Tarun

AU - Snyder,Shane A.

AU - Cizdziel,James V.

PY - 2017/2/1

Y1 - 2017/2/1

N2 - The Mississippi River drainage basin includes the Illinois, Missouri, Ohio, Tennessee, and Arkansas rivers. These rivers drain areas with different physiography, population centers, and land use, with each contributing a different suites of metals and wastewater contaminants that can affect water quality. In July 2012, we determined 18 elements (Be, Rb, Sr, Cd, Cs, Ba, Tl, Pb, Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn) and chlorophyll-a (Chl-a) in the five major tributaries and in the Upper Mississippi River. The following summer, we determined both trace elements and 25 trace organic compounds at 10 sites in a longitudinal study of the main stem of the Mississippi River from Grafton, Illinois to Natchez, Mississippi. We detected wastewater contaminants, including pharmaceuticals and endocrine disrupting compounds, throughout the river system, with the highest concentrations occurring near urban centers (St. Louis and Memphis). Concentrations were highest for atrazine (673 ng L−1), DEET (540 ng L−1), TCPP (231 ng L−1), and caffeine (202 ng L−1). The Illinois, Missouri, and Yazoo rivers, which drain areas with intense agriculture, had relatively high concentrations of Chl-a and atrazine. However, the Ohio River delivered higher loads of contaminants to the Mississippi River, including an estimated 177 kg day−1 of atrazine, due to higher flow volumes. Concentrations of heavy metals (Ni, V, Co, Cu, Cd, and Zn) were relatively high in the Illinois River and low in the Ohio River, although dissolved metal concentrations were below US EPA maximum contaminant levels for surface water. Multivariate analysis demonstrated that the rivers can be distinguished based on elemental and contaminant profiles.

AB - The Mississippi River drainage basin includes the Illinois, Missouri, Ohio, Tennessee, and Arkansas rivers. These rivers drain areas with different physiography, population centers, and land use, with each contributing a different suites of metals and wastewater contaminants that can affect water quality. In July 2012, we determined 18 elements (Be, Rb, Sr, Cd, Cs, Ba, Tl, Pb, Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn) and chlorophyll-a (Chl-a) in the five major tributaries and in the Upper Mississippi River. The following summer, we determined both trace elements and 25 trace organic compounds at 10 sites in a longitudinal study of the main stem of the Mississippi River from Grafton, Illinois to Natchez, Mississippi. We detected wastewater contaminants, including pharmaceuticals and endocrine disrupting compounds, throughout the river system, with the highest concentrations occurring near urban centers (St. Louis and Memphis). Concentrations were highest for atrazine (673 ng L−1), DEET (540 ng L−1), TCPP (231 ng L−1), and caffeine (202 ng L−1). The Illinois, Missouri, and Yazoo rivers, which drain areas with intense agriculture, had relatively high concentrations of Chl-a and atrazine. However, the Ohio River delivered higher loads of contaminants to the Mississippi River, including an estimated 177 kg day−1 of atrazine, due to higher flow volumes. Concentrations of heavy metals (Ni, V, Co, Cu, Cd, and Zn) were relatively high in the Illinois River and low in the Ohio River, although dissolved metal concentrations were below US EPA maximum contaminant levels for surface water. Multivariate analysis demonstrated that the rivers can be distinguished based on elemental and contaminant profiles.

KW - Atrazine

KW - Chlorophyll-a

KW - Mississippi River

KW - Trace elements

KW - Trace organic compounds

UR - http://www.scopus.com/inward/record.url?scp=85010280709&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85010280709&partnerID=8YFLogxK

U2 - 10.1007/s10661-017-5785-x

DO - 10.1007/s10661-017-5785-x

M3 - Article

VL - 189

JO - Environmental Monitoring and Assessment

T2 - Environmental Monitoring and Assessment

JF - Environmental Monitoring and Assessment

SN - 0167-6369

IS - 2

M1 - 73

ER -