Construction and Magnetic Study of a Trigonal-Prismatic Cobalt(II) Single-Ion Magnet

Binling Yao, Yi Fei Deng, Tianran Li, Jin Xiong, Bing Wu Wang, Zhiping Zheng, Yuan Zhu Zhang

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

A new tripodal hexadentate ligand of tris[6-(1H-pyrazol-1-yl)pyridin-2-yl]methanol (tppm) was synthesized and explored for constructing the trigonal-prismatic cobalt(II) complex [Co(tppm)][ClO4]2·2CH3CN·H2O (1). Magnetic study showed that 1 exhibited large uniaxial magnetic anisotropy with a zero-field-splitting parameter of -80.7 cm-1 and typical single-molecule-magnet behavior.

Original languageEnglish (US)
Pages (from-to)14047-14051
Number of pages5
JournalInorganic Chemistry
Volume57
Issue number22
DOIs
StatePublished - Nov 19 2018

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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