Controlled, stepwise reduction and band gap manipulation of graphene oxide

Akshay Mathkar, Dylan Tozier, Paris Cox, Peijie Ong, Charudatta Galande, Kaushik Balakrishnan, Arava Leela Mohana Reddy, Pulickel M. Ajayan

Research output: Contribution to journalArticle

279 Scopus citations

Abstract

Graphene oxide (GO) has drawn tremendous interest as a tunable precursor in numerous areas, due to its readily manipulable surface. However, its inhomogeneous and nonstoichiometric structure makes achieving chemical control a major challenge. Here, we present a room-temperature based, controlled method for the stepwise reduction of GO, with evidence of sequential removal of each organic moiety. By analyzing signature infrared absorption frequencies, we identify the carbonyl group as the first to be reduced, while the tertiary alcohol takes the longest to be completely removed from the GO surface. Controlled reduction allows for progressive tuning of the optical gap from 3.5 eV down to 1 eV, while XPS spectra show a concurrent increase in the C/O ratio. This study is the first step toward selectively enhancing the chemical homogeneity of GO, thus providing greater control over its structure, and elucidating the order of removal of functional groups and hydrazine-vapor reduction.

Original languageEnglish (US)
Pages (from-to)986-991
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume3
Issue number8
DOIs
StatePublished - Apr 19 2012
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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    Mathkar, A., Tozier, D., Cox, P., Ong, P., Galande, C., Balakrishnan, K., Leela Mohana Reddy, A., & Ajayan, P. M. (2012). Controlled, stepwise reduction and band gap manipulation of graphene oxide. Journal of Physical Chemistry Letters, 3(8), 986-991. https://doi.org/10.1021/jz300096t