Cosolvency. I. Some Non-Hydrogen Bonding Solutes with Non-Hydrogen Bonding Solvents

Monica Chawla, Rodolfo Pinal, Kenneth R. Morris, SAmuel H. Yalkowsky

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

The solubility data for a series of non-hydrogen bonding, monosubstituted benzenes in binary mixtures of water and non-hydrogen bonding cosolvents is presented. Good correlation between log solubility and fraction cosolvent is obtained, therefore the estimation of solubility in mixed solvents by a log-linear relationship can be attained. Slight positive or negative deviations from predicted solubility values are seen at high volume fractions of cosolvents. These deviations are attributed to the cosolvent-water interactions.

Original languageEnglish (US)
Pages (from-to)237-247
Number of pages11
JournalToxicological & Environmental Chemistry
Volume15
Issue number4
DOIs
StatePublished - Jul 1 1987

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Keywords

  • Solubility data
  • cosolvency
  • non-hydrogen bonding solutes
  • substituted benzenes

ASJC Scopus subject areas

  • Environmental Chemistry
  • Pollution
  • Health, Toxicology and Mutagenesis

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