Cosolvency. I. Some Non-Hydrogen Bonding Solutes with Non-Hydrogen Bonding Solvents

Monica Chawla, Rodolfo Pinal, Kenneth R. Morris, Samuel H Yalkowsky

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The solubility data for a series of non-hydrogen bonding, monosubstituted benzenes in binary mixtures of water and non-hydrogen bonding cosolvents is presented. Good correlation between log solubility and fraction cosolvent is obtained, therefore the estimation of solubility in mixed solvents by a log-linear relationship can be attained. Slight positive or negative deviations from predicted solubility values are seen at high volume fractions of cosolvents. These deviations are attributed to the cosolvent-water interactions.

Original languageEnglish (US)
Pages (from-to)237-247
Number of pages11
JournalToxicological and Environmental Chemistry
Volume15
Issue number4
DOIs
StatePublished - Jul 1 1987

Fingerprint

Solubility
solute
solubility
Water
Binary mixtures
Benzene
benzene
Volume fraction
water

Keywords

  • cosolvency
  • non-hydrogen bonding solutes
  • Solubility data
  • substituted benzenes

ASJC Scopus subject areas

  • Environmental Chemistry
  • Health, Toxicology and Mutagenesis
  • Pollution

Cite this

Cosolvency. I. Some Non-Hydrogen Bonding Solutes with Non-Hydrogen Bonding Solvents. / Chawla, Monica; Pinal, Rodolfo; Morris, Kenneth R.; Yalkowsky, Samuel H.

In: Toxicological and Environmental Chemistry, Vol. 15, No. 4, 01.07.1987, p. 237-247.

Research output: Contribution to journalArticle

Chawla, Monica ; Pinal, Rodolfo ; Morris, Kenneth R. ; Yalkowsky, Samuel H. / Cosolvency. I. Some Non-Hydrogen Bonding Solutes with Non-Hydrogen Bonding Solvents. In: Toxicological and Environmental Chemistry. 1987 ; Vol. 15, No. 4. pp. 237-247.
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