Cyclopentadienyl ring methylation and its effect on Si-H bond activation in (η5-C5H5-n(CH3) n)Mn(CO)2HSiH(C6H5)2 (n = 0, 1, 5) complexes

Dennis L Lichtenberger, Anjana Rai-Chaudhuri

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh 2, (η5-O5H4CH3)Mn(CO) 2HSiHPh2, and (η5-C5(CH3)5)Mn(CO) 2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.

Original languageEnglish (US)
Pages (from-to)1686-1690
Number of pages5
JournalOrganometallics
Volume9
Issue number5
StatePublished - 1990

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methylation
Methylation
Carbon Monoxide
photoelectrons
Chemical activation
transition metals
activation
rings
interactions
Photoelectrons
Transition metals

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

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Cyclopentadienyl ring methylation and its effect on Si-H bond activation in (η5-C5H5-n(CH3) n)Mn(CO)2HSiH(C6H5)2 (n = 0, 1, 5) complexes. / Lichtenberger, Dennis L; Rai-Chaudhuri, Anjana.

In: Organometallics, Vol. 9, No. 5, 1990, p. 1686-1690.

Research output: Contribution to journalArticle

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abstract = "The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh 2, (η5-O5H4CH3)Mn(CO) 2HSiHPh2, and (η5-C5(CH3)5)Mn(CO) 2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.",
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AB - The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh 2, (η5-O5H4CH3)Mn(CO) 2HSiHPh2, and (η5-C5(CH3)5)Mn(CO) 2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.

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