Cyclopentadienyl Ring Methylatlon and Its Effect on Si-H Bond Activation in (η5-C5H5-n(CH3)n)mn(co)2hsih(cehs)2 (n = 0, 1, 5) complexes

Dennis L. Lichtenbergerc, Anjana Rai-Chaudhuri

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh2, (η5-C5H4CH3)Mn(CO)2HSiHPh2, and (η5-C5(CH3)5)Mn(CO)2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.

Original languageEnglish (US)
Pages (from-to)1686-1690
Number of pages5
JournalOrganometallics
Volume9
Issue number5
DOIs
StatePublished - Jan 1 1990

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Cyclopentadienyl Ring Methylatlon and Its Effect on Si-H Bond Activation in (η<sup>5</sup>-C<sub>5</sub>H<sub>5-n</sub>(CH<sub>3</sub>)n)mn(co)<sub>2</sub>hsih(cehs)<sub>2</sub> (n = 0, 1, 5) complexes'. Together they form a unique fingerprint.

  • Cite this