Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts

Michael L. Szalai, Dominic V Mcgrath, David R. Wheeler, Thomas Zifer, James R. McElhanon

Research output: Contribution to journalArticle

95 Citations (Scopus)

Abstract

Thermally labile dendrimers based on the reversible furan-maleimide Diels-Alder reaction are described. First through fourth generation benzyl aryl ether based dendrons 3a-d that contained furan moieties at their focal point were allowed to react with bismaleimide central linker 4 to provide the corresponding dendrimers 5-8. Thermal degradation and reassembly of these dendrimers were studied under a variety of conditions and monitored by GPC and NMR.

Original languageEnglish (US)
Pages (from-to)818-823
Number of pages6
JournalMacromolecules
Volume40
Issue number4
DOIs
StatePublished - Feb 20 2007

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Dendrimers
Ethers
Pyrolysis
Nuclear magnetic resonance
Ether
furan
maleimide

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts. / Szalai, Michael L.; Mcgrath, Dominic V; Wheeler, David R.; Zifer, Thomas; McElhanon, James R.

In: Macromolecules, Vol. 40, No. 4, 20.02.2007, p. 818-823.

Research output: Contribution to journalArticle

Szalai, ML, Mcgrath, DV, Wheeler, DR, Zifer, T & McElhanon, JR 2007, 'Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts', Macromolecules, vol. 40, no. 4, pp. 818-823. https://doi.org/10.1021/ma062093w
Szalai, Michael L. ; Mcgrath, Dominic V ; Wheeler, David R. ; Zifer, Thomas ; McElhanon, James R. / Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts. In: Macromolecules. 2007 ; Vol. 40, No. 4. pp. 818-823.
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