Detection of a CH₄ atmosphere on Pluto

Using a low-resolution spectrograph and a CCD array, a spectrum of Pluto from 0.58 to 1.06 μm was obtained. The spectrum had a resolution of ∼25 Å and a signal-to-noise ratio of ∼300. It showed CH₄ absorption bands at 6200, 7200, 7900, 8400, 8600, 8900 and 10,000 Å. The strongest of these bands was at 8900 Å with an absorption depth of 0.23. This band was heavily saturated, compared to the weaker bands, providing proof for the gaseous origin of the observed absorptions. By applying CH₄ band model parameters to our data, a total CH₄ abundance of 80 ± 20 m-am was derived. This translates into a one-way abundance of 27 ± 7 m-am and a CH₄ surface pressure of 1.5 × 10⁻⁴ atm. An upper limit to the total pressure of ∼0.05 atm could be set. First-order calculations on atmospheric escape showed that this methane atmosphere would be stable if the mass of Pluto is increased 50% over its current value and its radius is 1400 km. Alternatively a heavier gas mixed with the CH₄ atmosphere would aid its stability. The relatively large amount of gaseous CH₄ observed implies that the absorption bands recently reported at 1.7 and 2.3 μm are likely due to atmospheric CH₄ absorptions rather than surface frost as interpreted earlier.