Deuterium quadrupole coupling in BD3CO

Alice M. Murray, Stephen G Kukolich

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The hyperfine structure of the J = 1→0 rotational transitions of 10BH3CO, 11BH3CO, and 11BD3CO was observed with a molecular beam maser spectrometer. Rotational constants, quadrupole coupling, spin rotation, and spin-spin interaction constants were determined from the data analysis. The deuterium quadrupole coupling constant in 11BD3CO, was determined to be eQqaa(D) = -48.5±2.3 kHz and eQq zz(D) = 116.9±5.4 kHz. The procedure for determining the matrix elements of the spin-spin interaction between the equivalent deuterium nuclei is presented.

Original languageEnglish (US)
Pages (from-to)4312-4317
Number of pages6
JournalThe Journal of Chemical Physics
Volume77
Issue number9
StatePublished - 1982

Fingerprint

Deuterium
deuterium
quadrupoles
Masers
Molecular beams
Spectrometers
masers
hyperfine structure
molecular beams
interactions
spectrometers
nuclei
matrices

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Deuterium quadrupole coupling in BD3CO. / Murray, Alice M.; Kukolich, Stephen G.

In: The Journal of Chemical Physics, Vol. 77, No. 9, 1982, p. 4312-4317.

Research output: Contribution to journalArticle

Murray, Alice M. ; Kukolich, Stephen G. / Deuterium quadrupole coupling in BD3CO. In: The Journal of Chemical Physics. 1982 ; Vol. 77, No. 9. pp. 4312-4317.
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