Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study

S. Carles; C. Desfrançois; J. P. Schermann; A. F. Jalbout; Ludwik Adamowicz

doi:10.1016/S0009-2614(00)01455-X

Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study

S. Carles, C. Desfrançois, J. P. Schermann, A. F. Jalbout, Ludwik Adamowicz

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Rydberg electron transfer spectroscopy (RET) has been used to determine the dipole-bound (DB) electron affinity (EA) of 1,3-butanediol and a single spectral feature was obtained corresponding to the EA value of 8±1 meV. A series of high-level ab initio calculations were also carried out for this system. They revealed an interesting configuration landscape of the 1,3-butanediol DB anion with four minima corresponding to different configurations. All four configurations can be responsible for the single RET spectral peak.

Original language	English (US)
Pages (from-to)	374-380
Number of pages	7
Journal	Chemical Physics Letters
Volume	334
Issue number	4-6
DOIs	https://doi.org/10.1016/S0009-2614(00)01455-X
State	Published - Feb 9 2001

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study",

abstract = "Rydberg electron transfer spectroscopy (RET) has been used to determine the dipole-bound (DB) electron affinity (EA) of 1,3-butanediol and a single spectral feature was obtained corresponding to the EA value of 8±1 meV. A series of high-level ab initio calculations were also carried out for this system. They revealed an interesting configuration landscape of the 1,3-butanediol DB anion with four minima corresponding to different configurations. All four configurations can be responsible for the single RET spectral peak.",

author = "S. Carles and C. Desfran{\c c}ois and Schermann, {J. P.} and Jalbout, {A. F.} and Ludwik Adamowicz",

note = "Funding Information: This work was partially supported in part by a grant from the National Science Foundation.",

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T1 - Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study

AU - Carles, S.

AU - Desfrançois, C.

AU - Schermann, J. P.

AU - Jalbout, A. F.

AU - Adamowicz, Ludwik

N1 - Funding Information: This work was partially supported in part by a grant from the National Science Foundation.

PY - 2001/2/9

Y1 - 2001/2/9

N2 - Rydberg electron transfer spectroscopy (RET) has been used to determine the dipole-bound (DB) electron affinity (EA) of 1,3-butanediol and a single spectral feature was obtained corresponding to the EA value of 8±1 meV. A series of high-level ab initio calculations were also carried out for this system. They revealed an interesting configuration landscape of the 1,3-butanediol DB anion with four minima corresponding to different configurations. All four configurations can be responsible for the single RET spectral peak.

AB - Rydberg electron transfer spectroscopy (RET) has been used to determine the dipole-bound (DB) electron affinity (EA) of 1,3-butanediol and a single spectral feature was obtained corresponding to the EA value of 8±1 meV. A series of high-level ab initio calculations were also carried out for this system. They revealed an interesting configuration landscape of the 1,3-butanediol DB anion with four minima corresponding to different configurations. All four configurations can be responsible for the single RET spectral peak.

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Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study

Abstract

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