Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study

S. Carles, C. Desfrançois, J. P. Schermann, A. F. Jalbout, Ludwik Adamowicz

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Rydberg electron transfer spectroscopy (RET) has been used to determine the dipole-bound (DB) electron affinity (EA) of 1,3-butanediol and a single spectral feature was obtained corresponding to the EA value of 8±1 meV. A series of high-level ab initio calculations were also carried out for this system. They revealed an interesting configuration landscape of the 1,3-butanediol DB anion with four minima corresponding to different configurations. All four configurations can be responsible for the single RET spectral peak.

Original languageEnglish (US)
Pages (from-to)374-380
Number of pages7
JournalChemical Physics Letters
Volume334
Issue number4-6
DOIs
StatePublished - Feb 9 2001

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Electron affinity
Anions
electron transfer
Spectroscopy
dipoles
anions
electron affinity
Electrons
configurations
spectroscopy
1,3-butylene glycol

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study. / Carles, S.; Desfrançois, C.; Schermann, J. P.; Jalbout, A. F.; Adamowicz, Ludwik.

In: Chemical Physics Letters, Vol. 334, No. 4-6, 09.02.2001, p. 374-380.

Research output: Contribution to journalArticle

Carles, S. ; Desfrançois, C. ; Schermann, J. P. ; Jalbout, A. F. ; Adamowicz, Ludwik. / Dipole-bound anion of 1,3-butanediol. Ab initio and Rydberg electron transfer spectroscopy study. In: Chemical Physics Letters. 2001 ; Vol. 334, No. 4-6. pp. 374-380.
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