Direct hydrolytic route to molecular oxo-hydroxo lanthanide clusters

Ruiyao Wang, Michael D. Carducci, Zhiping Zheng

Research output: Contribution to journalArticle

96 Scopus citations

Abstract

Direct hydrolysis of Er(NO3)3, Nd(ClO4)3, and Gd-(ClO4)3 with aqueous NaOH afforded three hexanuclear lanthanide clusters with a common octahedral core of [Ln66-O)(μ3-OH)8]8+ whose six lanthanide ions center on a μ6-oxo ligand. Each of the triangular faces of the octahedron is capped by a μ3-OH ligand, and the coordination sphere of the metal is completed by both aqua and NO3- ligands (1), aqua ligands only (2), and both aqua and ClO4- ligands (3).

Original languageEnglish (US)
Pages (from-to)1836-1837
Number of pages2
JournalInorganic Chemistry
Volume39
Issue number9
DOIs
Publication statusPublished - May 1 2000

    Fingerprint

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this