Dissolution of copper thin films in hydroxylamine-based solutions

Wayne Huang, Subramanian Tamilmani, Srini Raghavan, Robert Small

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Chemical mechanical planarization (CMP) of copper, a key processing step in the rapid development of copper interconnect technology, requires the use of a chemical system that can oxidize and complex copper. Hydroxylamine, because of its redox properties and copper complexation ability, is being actively tested for use in copper CMP. Fundamental investigations have been carried out to characterize the dissolution of electroplated copper thin films in hydroxylamine-based solutions. Based on potential-pH diagrams and the data on dependence of copper etch rate on pH, a mechanism for copper dissolution based on the auto-oxidation/reduction of hydroxylamine has been proposed. The effectiveness of benzotriazole (BTA) and salicylhydroxamic acid (SHA) as corrosion inhibitors for copper in hydroxylamine-based chemistries is discussed.

Original languageEnglish (US)
Pages (from-to)365-372
Number of pages8
JournalInternational Journal of Mineral Processing
Volume72
Issue number1-4
DOIs
StatePublished - Sep 29 2003

Fingerprint

Hydroxylamine
Copper
Dissolution
dissolution
copper
Thin films
Chemical mechanical polishing
Corrosion inhibitors
Complexation
complexation
diagram
Acids
acid

Keywords

  • Copper CMP
  • Corrosion inhibitors
  • Hydroxylamine

ASJC Scopus subject areas

  • Earth and Planetary Sciences(all)
  • Geochemistry and Petrology
  • Geotechnical Engineering and Engineering Geology

Cite this

Dissolution of copper thin films in hydroxylamine-based solutions. / Huang, Wayne; Tamilmani, Subramanian; Raghavan, Srini; Small, Robert.

In: International Journal of Mineral Processing, Vol. 72, No. 1-4, 29.09.2003, p. 365-372.

Research output: Contribution to journalArticle

Huang, Wayne ; Tamilmani, Subramanian ; Raghavan, Srini ; Small, Robert. / Dissolution of copper thin films in hydroxylamine-based solutions. In: International Journal of Mineral Processing. 2003 ; Vol. 72, No. 1-4. pp. 365-372.
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