Effect of sound frequency and initial concentration on the sonochemical degradation of perfluorooctane sulfonate (PFOS)

Lucia Rodriguez-Freire, Rajesh Balachandran, Maria Reye Sierra Alvarez, Manish K Keswani

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Perfluoooctanesulfonic acid (PFOS) is a perfluorinated compound (PFC) highly resistant to conventional advance oxidation processes, which was widely used in industrial activities due to its surfactant nature, olephobic-hydrophobic properties, and chemical inertness. Sonochemical treatment has been suggested as an effective approach to treat aqueous solutions containing minimal levels of PFCs. This study investigates PFOS sonochemical degradation and its dependency on the initial concentration (10-460. μM), and the applied sound frequency (25 and 500. kHz, and 1. MHz). PFOS was degraded by sonochemical treatment at concentrations as high as 460. μM, as demonstrated by fluoride release and total organic content data. PFOS degradation rate was higher at megasonic frequencies (1. MHz) compared to ultrasonic frequencies (25-500. kHz). PFOS degradation was controlled by saturation kinetics as indicated by an increase in PFOS degradation rate with increasing PFOS concentration until a maximum, after which the degradation rate was independent of the concentration. The saturation conditions were dependent on the sound frequency, and they were reached at a lower concentration under 1. MHz (100. μM) compared to the 500. kHz frequency (>460. μM). Overall, the results of this study demonstrate that high PFOS concentration can be effectively sonochemically treated using megasonic frequencies.

Original languageEnglish (US)
Pages (from-to)662-669
Number of pages8
JournalJournal of Hazardous Materials
Volume300
DOIs
StatePublished - Dec 1 2015

Fingerprint

sulfonate
Acoustic waves
Degradation
degradation
saturation
Surface active agents
Ultrasonics
effect
sound
perfluorooctane sulfonic acid
Fluorides
Surface-Active Agents
fluoride
surfactant
Oxidation
Kinetics
Acids
aqueous solution
oxidation
kinetics

Keywords

  • Kinetics
  • Megasonic
  • Perfluorocarbons
  • PFOS
  • Sonochemistry
  • Sonolysis
  • Ultrasonic

ASJC Scopus subject areas

  • Health, Toxicology and Mutagenesis
  • Pollution
  • Waste Management and Disposal
  • Environmental Chemistry
  • Environmental Engineering

Cite this

Effect of sound frequency and initial concentration on the sonochemical degradation of perfluorooctane sulfonate (PFOS). / Rodriguez-Freire, Lucia; Balachandran, Rajesh; Sierra Alvarez, Maria Reye; Keswani, Manish K.

In: Journal of Hazardous Materials, Vol. 300, 01.12.2015, p. 662-669.

Research output: Contribution to journalArticle

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