Effects of solvation and core switching on the photoelectron angular distributions from (CO 2) n - and (CO 2) n -·H 2O

Richard Mabbs, Eric Surber, Luis Velarde, Andrei M Sanov

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

The photodetachment of carbon-dioxide cluster anions with a special emphasis on the photoelectron angular distributions (PAD) was investigated. The imaging approach allowed a systematic examination of PAD which reflected the orbital nature of the different core structures. The study of PAD showed that solvation by several carbon-dioxide molecular and/or one water molecule has only moderate effect on the excess-electron orbitals. The observed PAD character was reconciled with the symmetry properties of the parent molecular orbitals, and the results showed remarkable similarities between the monomer and dimer anion cluster-core types.

Original languageEnglish (US)
Pages (from-to)5148-5154
Number of pages7
JournalThe Journal of Chemical Physics
Volume120
Issue number11
DOIs
StatePublished - Mar 15 2004

Fingerprint

Angular distribution
Solvation
Carbon Monoxide
Photoelectrons
solvation
photoelectrons
angular distribution
Carbon Dioxide
Anions
carbon dioxide
anions
electron orbitals
photodetachment
Molecular orbitals
Dimers
molecular orbitals
monomers
examination
Monomers
dimers

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Effects of solvation and core switching on the photoelectron angular distributions from (CO 2) n - and (CO 2) n -·H 2O. / Mabbs, Richard; Surber, Eric; Velarde, Luis; Sanov, Andrei M.

In: The Journal of Chemical Physics, Vol. 120, No. 11, 15.03.2004, p. 5148-5154.

Research output: Contribution to journalArticle

@article{2564fc89e11a4f139aa40100668bbb9b,
title = "Effects of solvation and core switching on the photoelectron angular distributions from (CO 2) n - and (CO 2) n -·H 2O",
abstract = "The photodetachment of carbon-dioxide cluster anions with a special emphasis on the photoelectron angular distributions (PAD) was investigated. The imaging approach allowed a systematic examination of PAD which reflected the orbital nature of the different core structures. The study of PAD showed that solvation by several carbon-dioxide molecular and/or one water molecule has only moderate effect on the excess-electron orbitals. The observed PAD character was reconciled with the symmetry properties of the parent molecular orbitals, and the results showed remarkable similarities between the monomer and dimer anion cluster-core types.",
author = "Richard Mabbs and Eric Surber and Luis Velarde and Sanov, {Andrei M}",
year = "2004",
month = "3",
day = "15",
doi = "10.1063/1.1647535",
language = "English (US)",
volume = "120",
pages = "5148--5154",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "11",

}

TY - JOUR

T1 - Effects of solvation and core switching on the photoelectron angular distributions from (CO 2) n - and (CO 2) n -·H 2O

AU - Mabbs, Richard

AU - Surber, Eric

AU - Velarde, Luis

AU - Sanov, Andrei M

PY - 2004/3/15

Y1 - 2004/3/15

N2 - The photodetachment of carbon-dioxide cluster anions with a special emphasis on the photoelectron angular distributions (PAD) was investigated. The imaging approach allowed a systematic examination of PAD which reflected the orbital nature of the different core structures. The study of PAD showed that solvation by several carbon-dioxide molecular and/or one water molecule has only moderate effect on the excess-electron orbitals. The observed PAD character was reconciled with the symmetry properties of the parent molecular orbitals, and the results showed remarkable similarities between the monomer and dimer anion cluster-core types.

AB - The photodetachment of carbon-dioxide cluster anions with a special emphasis on the photoelectron angular distributions (PAD) was investigated. The imaging approach allowed a systematic examination of PAD which reflected the orbital nature of the different core structures. The study of PAD showed that solvation by several carbon-dioxide molecular and/or one water molecule has only moderate effect on the excess-electron orbitals. The observed PAD character was reconciled with the symmetry properties of the parent molecular orbitals, and the results showed remarkable similarities between the monomer and dimer anion cluster-core types.

UR - http://www.scopus.com/inward/record.url?scp=1842631253&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1842631253&partnerID=8YFLogxK

U2 - 10.1063/1.1647535

DO - 10.1063/1.1647535

M3 - Article

C2 - 15267384

AN - SCOPUS:1842631253

VL - 120

SP - 5148

EP - 5154

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 11

ER -