Electrochemical oxidation of perfluorobutane sulfonate using boron-doped diamond film electrodes

Zhaohui Liao, James Farrell

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

This research investigated oxidation of perfluorobutane sulfonate (PFBS) at a boron-doped diamond (BDD) film anode. PFBS oxidation produced carbon dioxide, sulfate, fluoride, and trace amounts of trifluoroacetic acid (TFA). Rate constants for PFBS oxidation as a function of current density and temperature were measured using a rotating disk electrode (RDE) reactor. Reaction rates in the RDE reactor were zeroth order with respect to PFBS concentration, which is indicative of a reaction limited by the availability of reactive sites. The apparent electron transfer coefficient and apparent activation energy were used to evaluate the rate-limiting step for PFBS oxidation. Density functional simulations were used to calculate the reaction energies and activation barriers for PFBS oxidation by hydroxyl radicals and by direct electron transfer. Simulation results indicated that the experiments were performed at sufficiently high overpotentials that the rate-limiting step was an activationless direct electron transfer reaction.

Original languageEnglish (US)
Pages (from-to)1993-1999
Number of pages7
JournalJournal of Applied Electrochemistry
Volume39
Issue number10
DOIs
StatePublished - Oct 2009

Fingerprint

Boron
Electrochemical oxidation
Diamond films
Oxidation
Electrodes
Rotating disks
Electrons
Trifluoroacetic acid
Trifluoroacetic Acid
Reaction rates
Rate constants
Carbon dioxide
Fluorides
Anodes
Carbon Dioxide
Current density
Hydroxyl Radical
Activation energy
Sulfates
Chemical activation

Keywords

  • Boron-doped diamond
  • Density functional theory
  • Oxidation
  • Perfluorooctane sulfonate

ASJC Scopus subject areas

  • Electrochemistry
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Electrochemical oxidation of perfluorobutane sulfonate using boron-doped diamond film electrodes. / Liao, Zhaohui; Farrell, James.

In: Journal of Applied Electrochemistry, Vol. 39, No. 10, 10.2009, p. 1993-1999.

Research output: Contribution to journalArticle

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