Electronic feshbach resonances created in soft x-ray-induced 02 dissociation

Vandana Sharma, Etienne Gagnon, Arvinder S. Sandhu, Robin Santra, Wen Li, Phay Ho, Predrag Ranitovic, C. Lewis Cocke, Margaret M. Murnane, Henry C. Kapteyn

Research output: Contribution to journalConference article

Abstract

When an atom or molecule is ionized by an x-ray, super-excited states can be created that then decay, or autoionize, by ejecting a second electron from the ion. Here we find that autoionization following soft x-ray photoionization of molecular oxygen follows a complex, multi-step, process[1]. By interrupting the autoionization process using a short laser pulse, we show that autoionization cannot occur until the internuclear separation of the fragments is greater than 30 Ångstroms. As the ion and excited neutral atom separate, we directly observe the birth of a new state. We follow the transformation of electronically bound states of the molecular ion into Feshbach resonances of the neutral oxygen atom that are characterized by both positive and negative binding energies. States with negative binding energies have not been predicted or observed in neutral atoms previously.

Original languageEnglish (US)
Article number022071
JournalJournal of Physics: Conference Series
Volume194
Issue number2
DOIs
StatePublished - Dec 24 2009
Event26th International Conference on Photonic, Electronic and Atomic Collisions - Kalamazoo, United States
Duration: Jul 22 2009Jul 28 2009

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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    Sharma, V., Gagnon, E., Sandhu, A. S., Santra, R., Li, W., Ho, P., Ranitovic, P., Lewis Cocke, C., Murnane, M. M., & Kapteyn, H. C. (2009). Electronic feshbach resonances created in soft x-ray-induced 02 dissociation. Journal of Physics: Conference Series, 194(2), [022071]. https://doi.org/10.1088/1742-6596/194/2/022071