Enantioselective discrimination of D-and L-phenylalanine by chiral polyaniline thin films

Jiaxing Huang, Veronica M. Egan, Hailan Guo, Jeong Yeol Yoon, Alejandro L. Briseno, Iris E. Rauda, Robin L. Garrell, Charles M. Knobler, Feimeng Zhou, Richard B. Kaner

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Abstract

An overview is given of the visual, circular dichroism (CD), and UV-vis evidence for chiral discrimination between D- and L-phenylalanine by (R)-camphorsulfonic acid ((R)-CSA) developed polyaniline. Kinetic studies using a flow-injection quartz crystal microbalance demonstrate quantitatively the enantioselective incorporation of L-phenylalanine over D-phenylalanine. These results support a re-doping type interaction between the de-doped polymer and L-phenylalanine.

Original languageEnglish (US)
Pages (from-to)1158-1161
Number of pages4
JournalAdvanced Materials
Volume15
Issue number14
DOIs
StatePublished - Jul 17 2003

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ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Huang, J., Egan, V. M., Guo, H., Yoon, J. Y., Briseno, A. L., Rauda, I. E., Garrell, R. L., Knobler, C. M., Zhou, F., & Kaner, R. B. (2003). Enantioselective discrimination of D-and L-phenylalanine by chiral polyaniline thin films. Advanced Materials, 15(14), 1158-1161. https://doi.org/10.1002/adma.200304835