Evaluation of the reduction of imidazophenazine dye derivatives under fast-atom-bombardment mass-spectrometric conditions

Marina V. Kosevich, Oleg A. Boryak, Vadim V. Orlov, Vadim S. Shelkovsky, Vitalij V. Chagovets, Stepan G. Stepanian, Viktor A. Karachevtsev, Ludwik Adamowicz

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Satellite [M + 2]+• and [M + 3]+ peaks accompanying the common peak of the protonated molecule [M + H]+ that are known to indicate the occurrence of a reduction process were observed in the fast atom bombardment (FAB) mass spectra of imidazophenazine dye derivatives in glycerol matrix. The distribution of the abundances in the [M + nH] + peak group varied noticeably for different derivatives. This indicated different levels of the reduction depending on the different structure variations of the studied molecules. In the search for correlations between the mass spectral pattern and the structural features of the dyes, ab initio HF/6-31++G** quantum chemical calculations were performed. They revealed that the abundances of the [M + 2]+• and [M + 3] + ions show growth proportional to the decrease of the energy of the lowest unoccupied molecular orbital, i.e. proportional to the increase of the electron affinity of the dye molecule. A method for rapid screening of reductive properties of sets of dye derivatives on the basis of the FAB mass spectral data is discussed.

Original languageEnglish (US)
Pages (from-to)113-123
Number of pages11
JournalJournal of Mass Spectrometry
Volume41
Issue number1
DOIs
StatePublished - Jan 2006

Fingerprint

Coloring Agents
Derivatives
Atoms
Molecules
Electron affinity
Molecular orbitals
Glycerol
Screening
Satellites
Electrons
Ions
Growth

Keywords

  • Electron affinity
  • FAB mass spectrometry
  • Imidazophenazine dyes
  • LUMO
  • Quantum chemical calculations
  • Reduction

ASJC Scopus subject areas

  • Organic Chemistry
  • Spectroscopy
  • Biophysics

Cite this

Evaluation of the reduction of imidazophenazine dye derivatives under fast-atom-bombardment mass-spectrometric conditions. / Kosevich, Marina V.; Boryak, Oleg A.; Orlov, Vadim V.; Shelkovsky, Vadim S.; Chagovets, Vitalij V.; Stepanian, Stepan G.; Karachevtsev, Viktor A.; Adamowicz, Ludwik.

In: Journal of Mass Spectrometry, Vol. 41, No. 1, 01.2006, p. 113-123.

Research output: Contribution to journalArticle

Kosevich, MV, Boryak, OA, Orlov, VV, Shelkovsky, VS, Chagovets, VV, Stepanian, SG, Karachevtsev, VA & Adamowicz, L 2006, 'Evaluation of the reduction of imidazophenazine dye derivatives under fast-atom-bombardment mass-spectrometric conditions', Journal of Mass Spectrometry, vol. 41, no. 1, pp. 113-123. https://doi.org/10.1002/jms.974
Kosevich, Marina V. ; Boryak, Oleg A. ; Orlov, Vadim V. ; Shelkovsky, Vadim S. ; Chagovets, Vitalij V. ; Stepanian, Stepan G. ; Karachevtsev, Viktor A. ; Adamowicz, Ludwik. / Evaluation of the reduction of imidazophenazine dye derivatives under fast-atom-bombardment mass-spectrometric conditions. In: Journal of Mass Spectrometry. 2006 ; Vol. 41, No. 1. pp. 113-123.
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