Examining metal-phosphorus bonds: Submillimeter spectroscopy of the CrP radical (X4Σ)

M. A. Burton, D. T. Halfen, Lucy M Ziurys

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The submillimeter spectrum of the CrP radical (X4Σ) has been recorded using direct absorption techniques in the frequency range 347–545 GHz. This study is the first pure rotational measurement of a metal-phosphide species. CrP was synthesized in an AC discharge in argon by the reaction of gas-phase chromium with phosphorus vapor, produced by a novel source. Twelve rotational transitions of CrP were measured, each consisting of four fine structure components. The spectra were analyzed using a Hund's case (b) Hamiltonian, and rotational, spin-spin, and spin-rotation constants determined. The 3d phosphides appear to resemble the corresponding nitrides in terms of bonding.

Original languageEnglish (US)
Pages (from-to)228-232
Number of pages5
JournalChemical Physics Letters
Volume708
DOIs
StatePublished - Sep 16 2018

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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