Experimental Study of Geopolymer Binder Synthesized with Copper Mine Tailings and Low-Calcium Copper Slag

Lino Manjarrez, Arash Nikvar-Hassani, Rasoul Shadnia, Lianyang Zhang

Research output: Contribution to journalArticle

Abstract

The use of waste materials in construction is gaining increasing interest due to the development of new technologies. This paper presents an experimental study on geopolymer binder produced with copper mine tailings (MT) and low-calcium slag (SG) for potential applications in road construction. The study systematically investigated the effects of water-to-solid ratio (w/s), SG content (0%, 25%, and 50%), sodium hydroxide (NaOH) concentration (5, 10 and 15 M), and the ratio of sodium silicate (SS) to sodium hydroxide (0.0, 0.5, 1.0, and 1.5) on the unconfined compressive strength (UCS) of synthesized geopolymer binder specimens. Scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) analyses were also performed to characterize the microstructure and phase composition of the geopolymer specimens. The results show that the inclusion of SG improves UCS and reduces the initial water content required for achieving a certain workability of the geopolymer paste. The geopolymer binder specimens prepared at 50% SG, 10-M NaOH, SS/NaOH=1.0, and cured at 60°C for seven days reached the highest UCS of 23.5 MPa. The geopolymer paste prepared at 50% SG, 15-M NaOH concentration, and SS/NaOH ratios of 0.5 and 1.0 showed flash setting, which led to poorer quality specimens and lower UCS. The SEM, EDS, and XRD analyses clearly showed the participation of iron dissolved from SG in the formation of geopolymer gels. This research helps promote the reuse of MT and SG through geopolymerization and contributes to the knowledge of geopolymer materials.

Original languageEnglish (US)
Article number04019156
JournalJournal of Materials in Civil Engineering
Volume31
Issue number8
DOIs
StatePublished - Aug 1 2019

Fingerprint

Geopolymers
Copper mines
Tailings
Slags
Binders
Copper
Calcium
Sodium
Compressive strength
Silicates
Sodium Hydroxide
Ointments
Energy dispersive spectroscopy
X ray diffraction
Road construction
Scanning electron microscopy
Adhesive pastes
Phase composition
Water content
Gels

Keywords

  • Compressive strength
  • Flash setting
  • Geopolymer
  • Low-calcium slag
  • Mine tailings

ASJC Scopus subject areas

  • Civil and Structural Engineering
  • Building and Construction
  • Materials Science(all)
  • Mechanics of Materials

Cite this

Experimental Study of Geopolymer Binder Synthesized with Copper Mine Tailings and Low-Calcium Copper Slag. / Manjarrez, Lino; Nikvar-Hassani, Arash; Shadnia, Rasoul; Zhang, Lianyang.

In: Journal of Materials in Civil Engineering, Vol. 31, No. 8, 04019156, 01.08.2019.

Research output: Contribution to journalArticle

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