External field control of condensed phase reactions

Peter Gross, Steven D. Schwartz

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

Control of tunneling in a symmetric double well coupled to a bath via an external field is demonstrated. Optimal control theory is employed to design a laser field which couples to the reaction coordinate and drives a localized wave packet on the reactant side to the product side at a specified target time τ. Both a very quantumlike system (high barrier) and a low barrier double well are examined; excellent results are obtained for a range of reduced bath viscosities. Analysis of the control fields and corresponding localization dynamics shows that the frequency components of the control field are more or less in resonance with eigenstates of the double well and that the laser field enhances the natural dynamics of the individual wells. Future extension to more complicated models where the field couples to the bath is discussed.

Original languageEnglish (US)
Pages (from-to)4843-4851
Number of pages9
JournalJournal of Chemical Physics
Volume109
Issue number12
DOIs
StatePublished - 1998

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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