FAST Li** plus ION CONDUCTION IN CHLORO-BORATE GLASSES.

D. P. Button, R. P. Tandon, H. L. Tuller, Donald R Uhlmann

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

Substitutions of Cl for O in lithium borate glasses of the type Li//2O-(LiCl)//2-B//2O//3 (Li//2Z equals 36. 4 m/o) were found to result in systematically increasing Li ion conductivity, and decreasing Tg and density. In contrast to earlier studies which implied no B-O network modification upon Cl addition, substantial changes were found as exemplified in Tg and density variations. The effect of Cl substitution was traced to a change in O/B ratio. Liquid-liquid immiscibility limited the vitreous domain of glasses formed with LiCl. This resulted in a leveling off of various physical parameters with composition in the two-phase domain.

Original languageEnglish (US)
Pages (from-to)297-306
Number of pages10
JournalJournal of Non-Crystalline Solids
Volume42
Issue number1-3
StatePublished - Oct 1980
Externally publishedYes

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Borates
borates
Substitution reactions
lithium borates
Ions
substitutes
conduction
Glass
leveling
glass
Liquids
liquids
ions
Lithium
solubility
Solubility
conductivity
Chemical analysis
lithium borate

ASJC Scopus subject areas

  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials

Cite this

Button, D. P., Tandon, R. P., Tuller, H. L., & Uhlmann, D. R. (1980). FAST Li** plus ION CONDUCTION IN CHLORO-BORATE GLASSES. Journal of Non-Crystalline Solids, 42(1-3), 297-306.

FAST Li** plus ION CONDUCTION IN CHLORO-BORATE GLASSES. / Button, D. P.; Tandon, R. P.; Tuller, H. L.; Uhlmann, Donald R.

In: Journal of Non-Crystalline Solids, Vol. 42, No. 1-3, 10.1980, p. 297-306.

Research output: Contribution to journalArticle

Button, DP, Tandon, RP, Tuller, HL & Uhlmann, DR 1980, 'FAST Li** plus ION CONDUCTION IN CHLORO-BORATE GLASSES.', Journal of Non-Crystalline Solids, vol. 42, no. 1-3, pp. 297-306.
Button, D. P. ; Tandon, R. P. ; Tuller, H. L. ; Uhlmann, Donald R. / FAST Li** plus ION CONDUCTION IN CHLORO-BORATE GLASSES. In: Journal of Non-Crystalline Solids. 1980 ; Vol. 42, No. 1-3. pp. 297-306.
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