Formation of droplets on nonvolatile soluble particles

V. Talanquer; D. W. Oxtoby

doi:10.1063/1.1613937

Formation of droplets on nonvolatile soluble particles

V. Talanquer, D. W. Oxtoby

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The structural and thermodynamic properties of droplets formed on soluble and partialy soluble particles composed of a fluid with an extremely low volatility were studied using density functional theory. The required supersaturation for activated nucleation was found to increase as the size of the soluble particle decreases. The solubility transition was found to exhibit various similarities with the deliquescence process of water soluble salts.

Original language	English (US)
Pages (from-to)	9121-9128
Number of pages	8
Journal	Journal of Chemical Physics
Volume	119
Issue number	17
DOIs	https://doi.org/10.1063/1.1613937
State	Published - Nov 1 2003

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Formation of droplets on nonvolatile soluble particles",

abstract = "The structural and thermodynamic properties of droplets formed on soluble and partialy soluble particles composed of a fluid with an extremely low volatility were studied using density functional theory. The required supersaturation for activated nucleation was found to increase as the size of the soluble particle decreases. The solubility transition was found to exhibit various similarities with the deliquescence process of water soluble salts.",

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AB - The structural and thermodynamic properties of droplets formed on soluble and partialy soluble particles composed of a fluid with an extremely low volatility were studied using density functional theory. The required supersaturation for activated nucleation was found to increase as the size of the soluble particle decreases. The solubility transition was found to exhibit various similarities with the deliquescence process of water soluble salts.

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Formation of droplets on nonvolatile soluble particles

Abstract

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