Formation of peptide bonds in space: A comprehensive study of formamide and acetamide in Sgr B2(N)

D. T. Halfen, V. Ilyushin, Lucy M Ziurys

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Extensive observations of acetamide (CH3CONH2) and formamide (NH2CHO) have been conducted toward Sgr B2(N) at 1, 2, and 3mm using the Submillimeter Telescope (SMT) and the 12m antenna of the Arizona Radio Observatory. Over the frequency range 65-280GHz, 132 transitions of acetamide have been observed as individual, distinguishable features, although in some cases they are partially blended. The unblended transitions in acetamide indicate V LSR= 63.2 2.8kms-1 and ΔV 1/2= 12.5 2.9kms-1, line parameters that are very similar to that of formamide (NH2CHO) and other organic species in Sgr B2(N). For formamide, 79 individual transitions were identified over the same frequency region. Rotational diagram analyses indicate the presence of two components for both species in Sgr B2(N). For acetamide, the colder component (Eu < 40K) exhibits a rotational temperature of T rot= 17 4K and a column density of N tot= 5.2 3.5× 10 13cm-2; the higher energy component has T rot= 171 4K and N tot= 6.4 4.7× 1014cm-2. In the case of formamide, T rot= 26 4K and N tot= 1.6 0.7× 1014cm-2 for the colder component with T rot= 134 17K and N tot= 4.0 ± 1.2× 10 14cm-2 for the warmer region. The fractional abundances of acetamide are f (H2)= 1.7× 10-11 and 2.1× 10-10 for the cold and warm components, and in formamide, f (H 2)= 5.3× 10-11 and 1.3× 10-10. The similarity between the abundances and distributions of CH3CONH 2 and NH2CHO suggests a synthetic connection. The abundance of acetamide, moreover, is only a factor of three lower than that of formaldehyde, and very similar to acetaldehyde and ketene. CH 3CONH2 is therefore one of the most abundant complex organic species in Sgr B2(N), and could be a possible source of larger peptide molecules, as opposed to amino acids.

Original languageEnglish (US)
Article number60
JournalAstrophysical Journal
Volume743
Issue number1
DOIs
StatePublished - Dec 10 2011

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peptide
peptides
acetaldehyde
formaldehyde
antenna
observatory
amino acid
diagram
radio
amino acids
observatories
antennas
frequency ranges
diagrams
energy
cold
telescopes
methylidyne
temperature
molecules

Keywords

  • astrobiology
  • astrochemistry
  • ISM: molecules
  • line: identification
  • methods: laboratory
  • molecular data

ASJC Scopus subject areas

  • Space and Planetary Science
  • Astronomy and Astrophysics

Cite this

Formation of peptide bonds in space : A comprehensive study of formamide and acetamide in Sgr B2(N). / Halfen, D. T.; Ilyushin, V.; Ziurys, Lucy M.

In: Astrophysical Journal, Vol. 743, No. 1, 60, 10.12.2011.

Research output: Contribution to journalArticle

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