Identification and characterization of 1,2-BN cyclohexene using microwave spectroscopy

Stephen G Kukolich, Ming Sun, Adam M. Daly, Wei Luo, Lev N. Zakharov, Shih Yuan Liu

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

1,2-BN cyclohexene has been produced from 1,2-BN cyclohexane through the loss of H<inf>2</inf> and characterized and identified using a pulsed-beam Fourier-transform microwave spectrometer. Microwave spectra were measured in the frequency range of 5.5-12.5 GHz, providing accurate rotational constants and quadrupole coupling strengths. Results of high level calculations allowed clear assignment of the spectra to 1,2-BN cyclohexene. Heating the initial compound, 1,2-BN cyclohexane, to 60 °C in a 1 atm neon stream results in the loss of H<inf>2</inf> and conversion to 1,2-BN cyclohexene and this appears to be the first characterization of this compound as the 1,2-BN cyclohexene monomer.

Original languageEnglish (US)
Pages (from-to)88-92
Number of pages5
JournalChemical Physics Letters
Volume639
DOIs
StatePublished - Oct 16 2015

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Microwave spectroscopy
cyclohexane
microwaves
microwave spectrometers
microwave spectra
neon
spectroscopy
Microwave spectrometers
monomers
quadrupoles
frequency ranges
Neon
heating
Fourier transforms
Monomers
Microwaves
Heating
cyclohexene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Physics and Astronomy(all)

Cite this

Identification and characterization of 1,2-BN cyclohexene using microwave spectroscopy. / Kukolich, Stephen G; Sun, Ming; Daly, Adam M.; Luo, Wei; Zakharov, Lev N.; Liu, Shih Yuan.

In: Chemical Physics Letters, Vol. 639, 16.10.2015, p. 88-92.

Research output: Contribution to journalArticle

Kukolich, Stephen G ; Sun, Ming ; Daly, Adam M. ; Luo, Wei ; Zakharov, Lev N. ; Liu, Shih Yuan. / Identification and characterization of 1,2-BN cyclohexene using microwave spectroscopy. In: Chemical Physics Letters. 2015 ; Vol. 639. pp. 88-92.
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